Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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- Problem 4 The reversible, exothermic, liquid phase, homogeneous reaction A ₹R is being carried out in two ideal CSTRs. Both reactors operate at 150°C. The molar flow rate of A entering the first CSTR is 55,000 mol/h, the concentration of A in this stream is 6.5 mol/L, and the concentration of R is zero. The fractional conversion of A in the outlet stream from the second CSTR is 0.75. The fractional conversion is based on the molar flow rate entering the first CSTR. The reaction is first order in both directions. The rate constant for the forward reaction is 1.3 h-¹ and the equilibrium constant based on concentration at 150°C is 10.0. If the volume of the second CSTR is 10,000 L, what is the required volume of the first CSTR?arrow_forwardWhich of the following situations can we consider a recycle stream for a process with reacting units? a. The reactants are highly miscible with the products. b. The feed is a mixture of valuable compounds known to be toxic to humans. c. Separation of reactants from the product requires state-of-the-art technology. d. Raw feed to the reactor is extremely valuable and is found to be non-toxic to humans.arrow_forwardCHEMICAL ENGINEERING CHEMICAL REACTION ENGINEERING QUESTIONarrow_forward
- When an exothermic reaction proceeds adiabatically in a mixed flow reactor (MFR), outline and explain the characteristic graph of the energy balance and material balance to show that multiple steady states may exist. Also, explain that among multiple steady states, there is an unstable steady state.arrow_forwardQ1// The elementary liquid-phase reaction A+B C, r=k CA CB is carried out in a batch reactor with a cooling coil to keep the reactor isothermal at 27 °C. The reactor is initially charged with equal concentrations of A and B and no C, CAO = CB0 = 2.0 mol/L. How long does it take to reach 95% conversion? Rate constant 0.01725 L/mol.min =arrow_forwardFollows an elementary rate law and is carried out isothermally in a flow system. Theconcentrations of the A and B streams are 2M before mixing. The volumetric flow rate ofeach stream is 5 dm3/min and the entering temperature is 300K. The streams are mixedimmediately before entering. Two reactors are available. One is a 200 dm3 CSTR that canbe heated to 77 °C or cooled to 0 °C, the other is a 800 dm3 PFR operated at 300 K thatcannot be heated or cooled. Note that k = 0.07 dm3/mol min at 300 K and E = 83.7 kJ/mola) Which reactor and what conditions do you recommend? Explain the reason of yourchoice (space available, operational complexity). Back up your reasoning with theappropriate calculations b) How long would it take to achieve 90% conversion in a 200 dm3 batch reactor withinitial concentrations CA0 = CB0 = 1M after mixing at a temperature of 77 °C?arrow_forward
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