Calculations: (Show your calculations in full.) 1. Calculate the number of moles of 4-diazobenzenesulfonic acid that could be produced in the first step from sulfanilic acid (or sulfanilic acid monohydrate) assuming that NaNO2, Na2CO3, HCI and NaOH are in excess. Include the overall reaction between sulfanilic acid and sodium nitrite to produce 4-diazobenzenesulfonic acid (see Figure 8). Reaction: (either draw the structural formulas as in the Figure or use the condensed structural formulas like NaNO2 etc): Calculation:

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter16: Aldehydes And Ketones
Section: Chapter Questions
Problem 16.47P: The base-promoted rearrangement of an -haloketone to a carboxylic acid, known as the Favorskii...
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Data you may need to do the question. 

Mass of Sulfanilic acid: 0.60 g 

Mass of NaNO2: 0.30 g 

Mass of Methyl Orange basic form and container: 32.55 g 

Mass of the container: 29.67 g 

Mass of Methyl Orange basic form : 2.88 g 

 

Calculations: (Show your calculations in full.)
1. Calculate the number of moles of 4-diazobenzenesulfonic acid that could be
produced in the first step from sulfanilic acid (or sulfanilic acid monohydrate) assuming
that NaNO2, Na2CO3, HCI and NaOH are in excess. Include the overall reaction
between sulfanilic acid and sodium nitrite to produce 4-diazobenzenesulfonic acid (see
Figure 8).
Reaction: (either draw the structural formulas as in the Figure or use the condensed
structural formulas like NaNO2 etc):
Calculation:
Transcribed Image Text:Calculations: (Show your calculations in full.) 1. Calculate the number of moles of 4-diazobenzenesulfonic acid that could be produced in the first step from sulfanilic acid (or sulfanilic acid monohydrate) assuming that NaNO2, Na2CO3, HCI and NaOH are in excess. Include the overall reaction between sulfanilic acid and sodium nitrite to produce 4-diazobenzenesulfonic acid (see Figure 8). Reaction: (either draw the structural formulas as in the Figure or use the condensed structural formulas like NaNO2 etc): Calculation:
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