1. In the reactions involving the three isomeric alcohols with the formula C4H9OH, describe what each of the following tests showed about reactivity of the -OH group and reactions of 1°, 2°, and 3° alcohols. • the test with neutral KMnO4 • the test with concentrated HCl 2. Predict how the fourth alcohol with the formula C4H10O would react if tested with: • 0.01 M KMnO4 • concentrated HCl at room temperature Extend Further Use your observations of the solutions formed in the previous experiments and your understanding of alcohols to complete a table like the one shown below. Research the melting and boiling points to verify your answers.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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1. In the reactions involving the three isomeric alcohols with the formula C4H9OH, describe
what each of the following tests showed about reactivity of the -OH group and reactions of 1°,
2°, and 3° alcohols.
• the test with neutral KMnO4
• the test with concentrated HCl
2. Predict how the fourth alcohol with the formula C4H10O would react if tested with:
• 0.01 M KMnO4
• concentrated HCl at room temperature
Extend Further
Use your observations of the solutions formed in the previous experiments and your
understanding of alcohols to complete a table like the one shown below. Research the melting
and boiling points to verify your answers.

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