Calculate the temperature at which the following reaction becomes spontaneous. Compound  ΔHof (kJmol)ΔHfo (kJmol)   ΔSo (JK ⋅ mol)ΔSo (JK ⋅ mol)  Cl2(g) 0.0 +223.1 ClNO2(g) +12.6 +272.2 NO(g) +91.3 +210.8 NO2(g) +33.2 +240.1 NOCl(g) +51.7 +261.7 PCl3(g) −287.2 +311.8 PCl5(g) −374.9 +364.6   PCl5(g) ↔ PCl3(g) + Cl2(g) (Answer with K unit

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter17: Chemcial Thermodynamics
Section: Chapter Questions
Problem 17.52QE
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Calculate the temperature at which the following reaction becomes spontaneous.

Compound  ΔHof (kJmol)ΔHfo (kJmol)   ΔSo (JK ⋅ mol)ΔSo (JK ⋅ mol) 
Cl2(g) 0.0 +223.1
ClNO2(g) +12.6 +272.2
NO(g) +91.3 +210.8
NO2(g) +33.2 +240.1
NOCl(g) +51.7 +261.7
PCl3(g)
−287.2
+311.8
PCl5(g)
−374.9
+364.6

 

PCl5(g) ↔ PCl3(g) + Cl2(g)

(Answer with K unit )

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