Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Calculate the standard free-energy change of a voltaic cell with a potential of 0.35 V under standard conditions. Assume that 2 moles of electrons are transferred in the balanced
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- A certain half-reaction has a standard reduction potential E=-0.22 V. An engineer proposes using this half-reaction at the cathode of a red galvanic cell that must provide at least 0.90 V of electrical power. The cell will operate under standard conditions. Note for advanced students: assume the engineer requires this half-reaction to happen at the cathode of the cell. O-0 Is there a minimum standard reduction potential that the half-reaction used at O yes, there is a minimum. Ov %3D red the anode of this cell can have? If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower Iimit, check the "no" box. no minimum ? Is there a maximum standard reduction O yes, there is a maximum. = Dv potential that the half-reaction used at red the anode of this cell can have? If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. no maximum By using the…arrow_forwardA certain half-reaction has a standard reduction potential Eed=+0.45 V. An engineer proposes using this half-reaction at the anode of a galvanic cell that must provide at least 1.40 V of electrical power. The cell will operate under standard conditions. Note for advanced students: assume the engineer requires this half-reaction to happen at the anode of the cell. olo Is there a minimum standard reduction potential that the half-reaction used at the cathode of this cell can have? yes, there is a minimum. E red Ov Ar If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower limit, check the "no" box. no minimum Is there a maximum standard reduction potential that the half-reaction used at the cathode of this cell can have? E = Ov yes, there is a maximum. red If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. no maximumarrow_forwardA certain metal M forms a soluble sulfate salt MSO4. Suppose the left half cell of a galvanic cell apparatus is filled with a 200. mM solution of MSO4 and the right half cell with a 4.00 M solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 20.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. 0 left right x10 X Sarrow_forward
- A galvanic (voltaic) cell consists of an inert platinum clectrode in a solution containing 1.0 M tin(IV) ion and 1.0M tin(II) ion, and another inert platinum clectrode in a solution containing 1.0 M iron(III) ion and 1.0M iron(II) ion, connected by a salt bridge. Calculate the standard potential for this cell at 25 °C. Standard reduction potentials can be found in the standard reduction potentials table. E: cell Varrow_forwardA certain half-reaction has a standard reduction potential E == 'red - 1.02 V. An engineer proposes using this half-reaction at the anode of a galvanic cell that must provide at least 0.80 V of electrical power. The cell will operate under standard conditions. Note for advanced students: assume the engineer requires this half-reaction to happen at the anode of the cell. Is there a minimum standard reduction potential that the half-reaction used at the cathode of this cell can have? If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower limit, check the "no" box. Is there a maximum standard reduction potential that the half-reaction used at the cathode of this cell can have? If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. By using the information in the ALEKS Data tab, write a balanced equation describing a half reaction that could be…arrow_forwardBalance the following reaction. Calculate the cell potential and Gibbs free energy of this reaction at standard conditions. Write the line representations for the Galvanic Cells, indicating the anode and cathode. Cl2 + Br- -> Cl- + Br2arrow_forward
- Pb(s) Determine which of the following statements about the cell shown are True or False. True The standard cell potential, o, equals 0.93 V. True As the reaction proceeds, the concentration of the silver ions decreases. False Cations move to the lead half-cell. True The mass of the silver electrode is increasing. True The silver half-cell is the cathode. False The cell, as represented by the line notation, is a voltaic cell. True True The lead electrode is the anode. Electrons are spontaneously produced in the silver half-cell. salt bridge Ag(s) Pb+2 So Pb2+2e → Pb(s) AS NO3 E--0.13V Ag + le → Ag(s) E° - +0.80V Pb(s) Pb2+ (1M) || Ag+ (1M) | Ag(s)arrow_forwardA certain metal M forms a soluble nitrate salt MNO33 . Suppose the left half cell of a galvanic cell apparatus is filled with a 5.00M solution of MNO33 and the right half cell with a 25.0mM solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 35.0°C. What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode.Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits.arrow_forwardA galvanic (voltaic) cell consists of an inert platinum electrode in a solution containing 1.0 M1.0 M tin(IV) ion and 1.0 M1.0 M tin(II) ion, and another inert platinum electrode in a solution containing 1.0 M1.0 M cerium(IV) ion and 1.0 M1.0 M cerium(III) ion, connected by a salt bridge. Calculate the standard potential for this cell at 25°C25°C. Standard reduction potentials can be found in the standard reduction potentials table.arrow_forward
- Consider the following galvanic cell: Li (s) | 0.095M LiCl (aq) || 0.032M Sn(NO3)2 (aq) | Sn (s) Using Appendix H in the textbook, determine the Ecell of this galvanic cell. 2.54 V - 2.88 V O -2.92 V 2.88 V 2.92 Varrow_forwardA voltaic electrochemical cell is constructed using the following reaction. The half-cell components are separated by a salt bridge. 21 (aq) + Cl2(g) → 2(s) + 2CI(aq) Write the reactions that take place at the anode and at the cathode, the direction in which the electrons migrate in the external circuit, and the direction the anions in the salt bridge migrate. Use smallest possible integer coefficients. If a box is not needed, leave it blank. Enter the reaction that takes place at the anode. Include state symbols: Enter the reaction that takes place at the cathode. Include state symbols: In the external circuit, electrons migrate v the Cl2 electrode v the I electrode. Anions migrate v the salt bridge v the Cl2 compartment.arrow_forwardBalance the following reaction. Calculate the cell potential and Gibbs free energy of this reaction at standard conditions. Write the line representations for the Galvanic Cells, indicating the anode and cathode. MnO4- + H+ + Ce3+ -> Ce4+ + Mn2+ + H2Oarrow_forward
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