Calculate the pressure (in atm) at which the freezing temperature of water is -20°C = 253 K. H₂O(s)→ H₂O(l) AH°f (= AHM) V solid 1.963x10-5 m³/mole Vliquid 1.800x10-5 m³/mole = = = Caution: signs and units 6010 J/mole at TM = 273 K, (fusion = melting) Assume AH°f, Av₁ = V₁ - Vs are constant · · 1 atm = 1.013×105 Pa = 1 atm

Chemistry: Principles and Reactions
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Author:William L. Masterton, Cecile N. Hurley
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Chapter8: Thermochemistry
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Can We use Clausius-Clapeyron Equation Here? Since Enthalpy Of Vaporisation Not given,But enthalpy of Fusion Given.
Calculate the pressure (in atm) at which the freezing temperature of water is -20°C = 253 K.
H₂O(s)→ H₂O(l) AH°f (= AHM)
V solid
1.963x10-5 m³/mole
Vliquid 1.800x10-5 m³/mole
=
=
=
Caution: signs and units
6010 J/mole at TM = 273 K,
(fusion = melting)
Assume AH°f, Av₁ = V₁ - Vs are constant · ·
1 atm
=
1.013x105 Pa
= 1 atm
Transcribed Image Text:Calculate the pressure (in atm) at which the freezing temperature of water is -20°C = 253 K. H₂O(s)→ H₂O(l) AH°f (= AHM) V solid 1.963x10-5 m³/mole Vliquid 1.800x10-5 m³/mole = = = Caution: signs and units 6010 J/mole at TM = 273 K, (fusion = melting) Assume AH°f, Av₁ = V₁ - Vs are constant · · 1 atm = 1.013x105 Pa = 1 atm
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