Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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- 3. Pressure and entropy of degenerate Fermi gas. (a) Show that a Fermi electron gas in the ground state exerts a pressure (3n²)2/3 h? (N\S/3 N\5/3 (90) 5 m V In a uniform decrease of the volume of a cube every orbital has its energy raised: The energy of an orbital is proportional to 1/L? or to 1/V213. (b) Find an expression for the entropy of a Fermi electron gas in the region z « Ep. Notice that o → 0 as t – 0.arrow_forwardUsing the data given below, estimate the enthalpy added to 1 kg of water that undergoes the following transformations: (a) from 0 °C to 90 °C at p = 105 Pa; (b) from 95 °C to 105 °C at p = 105 Pa; (hint: combine enthalpy of vaporization and enthalpy change as a result of heating for 10 °C, which can be based on enthalpy change for every 10 °C for liquid water) (c) from 95 °C to 105 °C at p = 1.2 ´105 Pa (similar to 2, but a different pressure condition).arrow_forwardQuestion 4 The volume-temperature relationship for liquid acetone in Perry's Chemical Engineers' Handbook 7th ed p. 2-131 (t is the temperature in °C) V = Vo(1 + a₁t + a₂t² + a3t³) Vo 1.228 x 10³ m³/kg, a₁ = 1.3240 x10-³ a₂ = 3.8090 x 10-6, a3 = - 0.87983 x 10-8 ән Calculate (3) and (25) at Tutorial at T = 300 Karrow_forward
- 2. Consider the P-x-y diagram at 300 K for A-B mixtures at right. (a) What are the vapor pressures of A and B at 300 K? (b) A 25 mol-% A vapor mixture is isother- mally compressed from 1.5 to 2.0 bar. Does a 2-phase mixture form, and if so, what is the mole fraction of A in each resulting phase? (c) Using data at the azeotrope, compute the van Laar parameters a and 3 for A-B mix- tures at this temperature. P (bar) 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 XA or YAarrow_forwardConsider the following samples of gas.Select the set of graphs below that show the distributions of the speed of the atoms in each sample (please take a photo of the correct graph).arrow_forward2. Find the boiling pressure of acetone (mmHg) at 45 °C using: (b) AHap from Problem 1 (you may also assume that ZV-ZL ~ 1). -, Antoine equation, log10 pat = A- B T+C where Pat is in mmHg and T is in °C. For acetone between -13 and 55 °C: A = 7.11714, B = 1210.6, and C=229.66. (c) ( > "Shortcut" equation log10 Pat a² = (1 + w) (1 - // ) For acetone: T=508.2 K, P = 4.701 MPa, w=0.306.arrow_forward
- The partial molar enthalpy of component (1) in a binary mixture at a stant temperature and pressure is given as H₂ = x₂ − x₁ +4, (2.1) ere x₁ and x₂ are the mole fraction of components (1) and (2) in the mixture. If the molar halpy of component (1) in a pure case is H₁ = 20 kJ/mol. Determine (10 points) the partial molar enthalpy of component (2). (10 points) molar enthalpy of the mixture. Carrow_forward13 An ideal solution of 5.25 moles of benzene and 3.0 moles of toluene is placed in a piston and cylinder assembly. At 298 K, the vapor pressure of pure substances are P°(benzene) = 96.4 torr & P°(toluene) = 28.9 torr. The vapor pressure of the solution is; 69.81 torr O 71.83 torr 53.47 torr O 66.61 torr 67.50 torrarrow_forwardmolar mass of ethanol: 46.094w = 0.645Tc = 513.9 KVc = 167cm^3/molTn = 351.4 K a.) Calculate the molar volume V (in cm3/mol) and compressibility factor Z of saturated liquid ethanol at T = 368 K.b.) Calculate the molar volume V (in cm3/mol) and compressibility factor Z of saturated vapor ethanol at T = 368 K.c.) Calculate the molar volume and compressibility factor Z of ethanol vapor at T = 462.5 K and P = 24.6 bar.arrow_forward
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