Calculate the frequency and wavenumber of the J = 2 ← 1 transition in the pure rotational spectrum of 12C16O. The equilibrium bond length is 112.81 pm. Would the frequency increase or decrease if centrifugal distortion is considered?

Calculate the frequency and wavenumber of the J = 2 ← 1 transition in the pure rotational spectrum of 12C16O. The equilibrium bond length is 112.81 pm. Would the frequency increase or decrease if centrifugal distortion is considered?

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter14: Rotational And Vibrational Spectroscopy

Section: Chapter Questions

Problem 14.1E

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Question

Calculate the frequency and wavenumber of the J = 2 ← 1 transition in the pure rotational spectrum of ¹²C¹⁶O. The equilibrium bond length is 112.81 pm. Would the frequency increase or decrease if centrifugal distortion is considered?

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