Calculate the frequencies and wavelengths for the rotational transition J = 0 → J = 1 and J = 4 → J = 5 for the HCl molecule. The internuclear distance is Re = 0.12745 nm. What is the frequency shift between the two isotopomers H35Cl and H37Cl for the two transitions?

Calculate the frequencies and wavelengths for the rotational transition J = 0 → J = 1 and J = 4 → J = 5 for the HCl molecule. The internuclear distance is Re = 0.12745 nm. What is the frequency shift between the two isotopomers H35Cl and H37Cl for the two transitions?

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter16: Introduction To Magnetic Spectroscopy

Section: Chapter Questions

Problem 16.17E

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Question

3 Calculate the frequencies and wavelengths for the rotational transition J = 0 → J = 1 and J = 4 → J = 5 for the HCl molecule. The internuclear distance is Re = 0.12745 nm. What is the frequency shift between the two isotopomers H35Cl and H37Cl for the two transitions?

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