Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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1) The molecule ClF; belongs to the point group shown below: C4v E 2C, C2 20, 20d A1 1 1 1 1 1 A2 1 1 1 -1 -1 B1 1 -1 1 1 -1 B2 1 -1 1 -1 1 E 0 (x, y) 2 0 -2 c) Draw pictures showing how a i) dy and a ii) d,2 orbital on Cl would transform under each operation of the group. What are their Mulliken symbols? d) What are the irreducible representations for the SALCS of the 5 fluorine 2s orbitals? You do not need to draw a diagram or order the orbitals by energy, but for each molecular orbital symmetry, list all atomic orbitals and SALCS with that symmetry. Example: If this question were asking about the composition of the MOs of water (C2, point group), your answer would include the following - a1: 2s (oxygen), H2 SALC, and 2p, (oxygen)
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Transcribed Image Text:1) The molecule ClF; belongs to the point group shown below: C4v E 2C, C2 20, 20d A1 1 1 1 1 1 A2 1 1 1 -1 -1 B1 1 -1 1 1 -1 B2 1 -1 1 -1 1 E 0 (x, y) 2 0 -2 c) Draw pictures showing how a i) dy and a ii) d,2 orbital on Cl would transform under each operation of the group. What are their Mulliken symbols? d) What are the irreducible representations for the SALCS of the 5 fluorine 2s orbitals? You do not need to draw a diagram or order the orbitals by energy, but for each molecular orbital symmetry, list all atomic orbitals and SALCS with that symmetry. Example: If this question were asking about the composition of the MOs of water (C2, point group), your answer would include the following - a1: 2s (oxygen), H2 SALC, and 2p, (oxygen)
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Step 1: Chracter table and SALC
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Step 2: Orbital picture
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Step 3: Irreducible represntation
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