By the Bransted-Lowry definition, acids are proton donors and bases are proton acceptors. By the Lewis definition, acids are electron-pair acceptors, and bases are electron-pair donors. For bases, the two definitions are equivalent such that all Lewis bases are Brensted- Lowry bases and vice versa. However, it is possible to have a Lewis acid that is not a Bronsted-Lowry acid. This is because Lewis acids include molecules and cations that have a vacant valence orbital, regardless of whether they have a proton to donate Common examples of Lewis acids (that are not Bransted-Lowry acids) are metal ions, such as AP and Cu²+ The following is an example of a Lewis acid-base reaction: Cu²+ +4NH3-Cu(NH₂), NH, donates the electron pair to Cu²+. Therefore, NH, is a Lewis base, and Cu²+ is a Lewis acid. Identify the Lewis acid in the following reaction: View Available Hint(s) Co²+ NH₁ Co(NH3)2+ Submit Part B Co*+(aq) +6NHs(aq) == Co[NH,)**(aq) Classify each of the following as a Lewis acid or a Lewis base. Drag the appropriate items to their respective bins. View Available Hint(s) OH NO₂ (CH₂)N SICU F M² Reset Help 18

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter4: Acids And Bases
Section: Chapter Questions
Problem 4.35AP: The sec-butyl cation can react as both a Brnsted-Lowry acid (a proton donor) and a Lewis acid (an...
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By the Bransted-Lowry definition, acids are proton
donors and bases are proton acceptors. By the Lewis
definition, acids are electron-pair acceptors, and bases
are electron-pair donors. For bases, the two definitions
are equivalent such that all Lewis bases are Brensted-
Lowry bases and vice versa.
However, it is possible to have a Lewis acid that is not a
Bronsted-Lowry acid. This is because Lewis acids
include molecules and cations that have a vacant
valence orbital, regardless of whether they have a proton
to donate.
Common examples of Lewis acids (that are not
Bransted-Lowry acids) are metal ions, such as AP and
Cu The following is an example of a Lewis acid-base
reaction:
Cu²+ +4NH, Cu(NH₂),
NH, donates the electron pair to Cu²+, Therefore,
NH, is a Lewis base, and Cu²+ is a Lewis acid.
Identify the Lewis acid in the following reaction:
View Available Hint(s)
Co²+
NH₂
Co(NH3)²+
Submit
Part B
Classify each of the following as a Lewis acid or a Lewis base.
Drag the appropriate items to their respective bins.
View Available Hint(s)
OH
NO₂
(CH₂) N
Co2+ (aq) +6NH, (aq) = Co(NH3)²(aq)
SICU
F
Mu
Reset Help
8
CO
=
Transcribed Image Text:By the Bransted-Lowry definition, acids are proton donors and bases are proton acceptors. By the Lewis definition, acids are electron-pair acceptors, and bases are electron-pair donors. For bases, the two definitions are equivalent such that all Lewis bases are Brensted- Lowry bases and vice versa. However, it is possible to have a Lewis acid that is not a Bronsted-Lowry acid. This is because Lewis acids include molecules and cations that have a vacant valence orbital, regardless of whether they have a proton to donate. Common examples of Lewis acids (that are not Bransted-Lowry acids) are metal ions, such as AP and Cu The following is an example of a Lewis acid-base reaction: Cu²+ +4NH, Cu(NH₂), NH, donates the electron pair to Cu²+, Therefore, NH, is a Lewis base, and Cu²+ is a Lewis acid. Identify the Lewis acid in the following reaction: View Available Hint(s) Co²+ NH₂ Co(NH3)²+ Submit Part B Classify each of the following as a Lewis acid or a Lewis base. Drag the appropriate items to their respective bins. View Available Hint(s) OH NO₂ (CH₂) N Co2+ (aq) +6NH, (aq) = Co(NH3)²(aq) SICU F Mu Reset Help 8 CO =
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