
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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A buffer solution is formed by adding 0.200 moles of solid potassium nitrite, KNO₂, to 500.0 ml of 0.500 M Nitrous acid, HNO₂ solution. You may assume that the change in volume is negligible upon addition of the solid.
pKa of HNO2 is 3.40
Ka of HNO2 is 4.0E-4
m.w. of HNO2 is 47.01 g/mol
pH of the buffer solution is 3.30, so now
Calculate the pH of the buffer solution after the addition of 5.00 ml of 2.50 M Ba(OH)₂.
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