Be sure to answer all parts. Nitric oxide occurs in the tropospheric nitrogen cycle, but it destroys ozone in the stratosphere. (a) Write equations for its reaction with ozone and for the reverse reaction. Include the physical states of the reactants and products. Forward reaction: Reverse reaction: (b) Given that the forward and reverse steps are first order in each component, write general rate laws for them. Let kç be the rate constant of the forward reaction and k. the rate constant of the reverse reaction. Forward rate law: Rate= kf Reverse rate law: Rate, = k, (c) Calculate AG for the forward reaction at 280. K, the average temperature in the stratosphere. (Assume that the AH and S values do not change with temperature.) kJ

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Chapter1: Chemical Foundations
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Be sure to answer all parts.
Nitric oxide occurs in the tropospheric nitrogen cycle, but it destroys ozone in the stratosphere.
(a) Write equations for its reaction with ozone and for the reverse reaction. Include the physical states
of the reactants and products.
Forward reaction:
Reverse reaction:
(b) Given that the forward and reverse steps are first order in each component, write general rate laws
for them. Let kç be the rate constant of the forward reaction and k. the rate constant of the reverse
reaction.
Forward rate law: Rate= kf
Reverse rate law: Rate, = k,
(c) Calculate AG for the forward reaction at 280. K, the average temperature in the stratosphere.
(Assume that the AH and S values do not change with temperature.)
kJ
Transcribed Image Text:Be sure to answer all parts. Nitric oxide occurs in the tropospheric nitrogen cycle, but it destroys ozone in the stratosphere. (a) Write equations for its reaction with ozone and for the reverse reaction. Include the physical states of the reactants and products. Forward reaction: Reverse reaction: (b) Given that the forward and reverse steps are first order in each component, write general rate laws for them. Let kç be the rate constant of the forward reaction and k. the rate constant of the reverse reaction. Forward rate law: Rate= kf Reverse rate law: Rate, = k, (c) Calculate AG for the forward reaction at 280. K, the average temperature in the stratosphere. (Assume that the AH and S values do not change with temperature.) kJ
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