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(b) (6 marks) Decide which 'H NMR spectrum (A) or (B) best fits 2-chlorophenol and 4-chlorophenol respectively. Justify your answer. Describe the 'H spin systems of both molecules using Pople notation. The lowest chemical shift for each molecule is from a proton alpha to the -OH group. Why is this the case when oxygen is more electronegative than chlorine? (A) OH CI OH 2-chlorophenol CI 4-chlorophenol 40 7.35 7.30 7.25 7.20 7.15 7.10 7.05 7.00 6.95 6.90 6.85 6.80 6.75 6. ppm (B) 40 7.35 7.30 7.25 7.20 7.15 7.10 7.05 ppm 7.00 6.78 Page 3 of 8

(b) (6 marks) Decide which 'H NMR spectrum (A) or (B) best fits 2-chlorophenol and 4-chlorophenol respectively. Justify your answer. Describe the 'H spin systems of both molecules using Pople notation. The lowest chemical shift for each molecule is from a proton alpha to the -OH group. Why is this the case when oxygen is more electronegative than chlorine? (A) OH CI OH 2-chlorophenol CI 4-chlorophenol 40 7.35 7.30 7.25 7.20 7.15 7.10 7.05 7.00 6.95 6.90 6.85 6.80 6.75 6. ppm (B) 40 7.35 7.30 7.25 7.20 7.15 7.10 7.05 ppm 7.00 6.78 Page 3 of 8

Understanding Business
Understanding Business
12th Edition
ISBN:9781259929434
Author:William Nickels
Publisher:William Nickels
Chapter1: Taking Risks And Making Profits Within The Dynamic Business Environment
Section: Chapter Questions
Problem 1CE
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(b) (6 marks) Decide which 'H NMR spectrum (A) or (B) best fits 2-chlorophenol and 4-chlorophenol respectively. Justify your answer. Describe the 'H spin systems of both molecules using Pople notation. The lowest chemical shift for each molecule is from a proton alpha to the -OH group. Why is this the case when oxygen is more electronegative than chlorine? (A) OH CI OH 2-chlorophenol CI 4-chlorophenol 40 7.35 7.30 7.25 7.20 7.15 7.10 7.05 7.00 6.95 6.90 6.85 6.80 6.75 6. ppm (B) 40 7.35 7.30 7.25 7.20 7.15 7.10 7.05 ppm 7.00 6.78 Page 3 of 8
Transcribed Image Text:(b) (6 marks) Decide which 'H NMR spectrum (A) or (B) best fits 2-chlorophenol and 4-chlorophenol respectively. Justify your answer. Describe the 'H spin systems of both molecules using Pople notation. The lowest chemical shift for each molecule is from a proton alpha to the -OH group. Why is this the case when oxygen is more electronegative than chlorine? (A) OH CI OH 2-chlorophenol CI 4-chlorophenol 40 7.35 7.30 7.25 7.20 7.15 7.10 7.05 7.00 6.95 6.90 6.85 6.80 6.75 6. ppm (B) 40 7.35 7.30 7.25 7.20 7.15 7.10 7.05 ppm 7.00 6.78 Page 3 of 8
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