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Understanding Business
12th Edition
ISBN: 9781259929434
Author: William Nickels
Publisher: McGraw-Hill Education
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(6 marks)
Decide which 'H NMR spectrum (A) or (B) best fits 2-chlorophenol and 4-chlorophenol
respectively. Justify your answer.
Describe the 'H spin systems of both molecules using Pople notation.
The lowest chemical shift for each molecule is from a proton alpha to the -OH group. Why is
this the case when oxygen is more electronegative than chlorine?
(A)
OH
CI
OH
2-chlorophenol
CI
4-chlorophenol
40
7.35
7.30
7.25
7.20
7.15
7.10
7.05
7.00
6.95
6.90 6.85
6.80
6.75
6.
ppm
(B)
40
7.35
7.30
7.25 7.20
7.15
7.10
7.05
ppm
7.00
6.78
Page 3 of 8"
Transcribed Image Text:(b)
(6 marks)
Decide which 'H NMR spectrum (A) or (B) best fits 2-chlorophenol and 4-chlorophenol
respectively. Justify your answer.
Describe the 'H spin systems of both molecules using Pople notation.
The lowest chemical shift for each molecule is from a proton alpha to the -OH group. Why is
this the case when oxygen is more electronegative than chlorine?
(A)
OH
CI
OH
2-chlorophenol
CI
4-chlorophenol
40
7.35
7.30
7.25
7.20
7.15
7.10
7.05
7.00
6.95
6.90 6.85
6.80
6.75
6.
ppm
(B)
40
7.35
7.30
7.25 7.20
7.15
7.10
7.05
ppm
7.00
6.78
Page 3 of 8
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