b) 1. Ho, Lindlar 2. Br₂, DCM (CH₂C₁₂) Skeletal Structure The reaction above produces two enantiomers. Show the Perspective Formulas of each: 1
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- plz explain why2. Use the Newman projection to identify the structure shown: (a) as a Fischer projection (b) as a bond-line structure (c) by name Circle your answer for each part. CH2CH3 F+ H CH(CH3)2 CH2CH3 H+ F CH(CH3)2 三F H CH2CH3 H H F no CH(CH3)2 geslaan sam o Y (S)-4-fluoro-2-methylhexane F (R)-4-fluoro-2-methylhexaneAssign the configuration to each asymmetric carbon as R or S. NO2 (b) NO2 (c) (d) OCH3 (a) Br
- (a) Classify each of the following pairs of structures as constitutional isomers, conformational isomers, configurational isomers or identical. Br and Br Br NH, CH, HO но H,C. ii. and CH, CH, Vi. and он Ph CH, он CH, Ph iv. and5. (a) Identify the relationship of the two compounds below. (b) Write the most stable chair conformation for each. Br CH₂ and A. identical B. constitutional isomers C. stereoisomers D. unrelated Br CH₂5) relationship between the pairs of structures. NOTE: Each term may be used more than Choose the term from the five terms listed below that BEST describes the once and not all terms need be used. Identical Diastereomers Enantiomers Constitutional isomers Not isomers CH3 CH3 ÇI H3C-Br CH3 Br -CI H,C. D-H H3C- Br H- -D Br CH3 -CI ČH3 OH H3C, CHO OHC, OH OH H. HO CHO OHC CH3 H. OH ÓH
- 3.) 2-Methylbutane (isopentane) is used, in conjunction with liquid nitrogen, to freeze tissues for cryosectioning in histology. Below is the potential energy diagram for all the conformers of 2-methylbutane. Provide structures that match structure A, B, and C in the boxes provided. B F IM C A potential energy Conformer A 0° D angle of internal rotation Conformer B E F H 360° (=0°) Conformer C39. The following compound A is less stable than compound B. Using your knowledge on the origin of angle strain and hybridization states of the carbon involved, explain this observation. CH3 less stable than CH₂ A B