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6) Calculate the absolute entropy for 1 mole of Ar gas (monatomic) with 22.4 liter volume at 273 K using Boltzmann's formula. What is the change in entropy if the temperature doubles while V is constant? What is the change in entropy if the volume doubles while T is constant? What is the change in entropy if both T and V double? (Note: To evaluate In(N!) use Stirling's asymptotic formula In(N!) ~ N In N – N ) S-k log W LVDWIG BOLTZMANN 18W-1906 DE FHILPAULA BOLTZMANN GER CAR

6) Calculate the absolute entropy for 1 mole of Ar gas (monatomic) with 22.4 liter volume at 273 K using Boltzmann's formula. What is the change in entropy if the temperature doubles while V is constant? What is the change in entropy if the volume doubles while T is constant? What is the change in entropy if both T and V double? (Note: To evaluate In(N!) use Stirling's asymptotic formula In(N!) ~ N In N – N ) S-k log W LVDWIG BOLTZMANN 18W-1906 DE FHILPAULA BOLTZMANN GER CAR

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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6) Calculate the absolute entropy for 1 mole of Ar gas (monatomic) with 22.4 liter volume at 273 K using Boltzmann's formula. What is the change in entropy if the temperature doubles while V is constant? What is the change in entropy if the volume doubles while T is constant? What is the change in entropy if both T and V double? (Note: To evaluate In(N!) use Stirling's asymptotic formula In(N!) ~ N In N – N ) S-k log W LVDWIG BOLTZMANN 18W-1906 DE FHILPAULA BOLTZMANN GER CAR
Transcribed Image Text:6) Calculate the absolute entropy for 1 mole of Ar gas (monatomic) with 22.4 liter volume at 273 K using Boltzmann's formula. What is the change in entropy if the temperature doubles while V is constant? What is the change in entropy if the volume doubles while T is constant? What is the change in entropy if both T and V double? (Note: To evaluate In(N!) use Stirling's asymptotic formula In(N!) ~ N In N – N ) S-k log W LVDWIG BOLTZMANN 18W-1906 DE FHILPAULA BOLTZMANN GER CAR
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