Acetic acid can be manufactured by combining methanolwith carbon monoxide, an example of a carbonylationreaction: CH3OH(l) + CO(g)----->CH3COOH(l) (a) Calculate the equilibrium constant for the reaction at25 °C. (b) Industrially, this reaction is run at temperaturesabove 25 °C. Will an increase in temperature produce anincrease or decrease in the mole fraction of acetic acid atequilibrium? Why are elevated temperatures used? (c) Atwhat temperature will this reaction have an equilibriumconstant equal to 1? (You may assume that ΔH° and ΔS ° aretemperature independent, and you may ignore any phasechanges that might occur.)

Given that Ka for HIO is 3.2 × 10-1" at 25 °C, what is the value of K, for IO¯ at 25 °C? Kp = Given that Kp for CH, NH, is 5.0 x 10-4 at 25 °C, what is the value of Ka for CH, NH; at 25 °C? Ka =

A mixture of 3 moles of NO and 4 moles of H2O is placed in a 5 L container and heated to 300 degrees C where the equilibrium 4NH3 (g) + 5O2 (g) ⇄ 4NO(g) + 6H2O(g) is established. At equilibrium, the NH3 , O2 , NO and H2O concentrations were 0.45, 0.5625, 0.15, and 0.125 moles/L, respectively. The volume of the container is then reduced from 5 L to 1 L. What is the equilibrium constant, Kc, after equilibrium is re-established at the reduced volume? a) 6.43x10-9 b) 1.20x106 c) 7.62x10-5 d) 3.94x108 e) 8.36x10-7

Write the Ke and Kp expressions for the following homogeneous equilibrium reactions: a) CO(g) + -O2(g) = CO2(g) b) 2CO,(g) = O,(g) + 2CO(g) c) N,0(g) = N2(g) + -0,(g)

Construct the expression for Kp for the following reaction. C(s) + 2 H₂(g) CH4(g)

Benzoic acid (C,H,COOH) dissolves in water to the extent of 2.00 g L¯1 at 15°C and in diethyl ether to the extent of 6.6 × 10² g L¯1 at the same temperature. (a) Calculate the equilibrium constants at 15°C for the two reactions C,H;COOH(s) 2 C,H;COOH(aq)

Consider the reaction: CH3COOH (aq) + H₂O(1) K = 1.8 x 10-5 at 25 °C Part A If a solution initially contains 0.225 mol L-¹ CH3COOH, what is the equilibrium concentration of H3O+ at 25 °C? Express your answer in moles per litre to two significant figures. 15. ΑΣΦ [H3O+] = H3O+(aq) + CH3COO (aq) Submit Request Answer ? mol L-1

Predict the change in the preturbations table below. Also decide whether the equilibrium shifts to the right or left.

Water gas is a 1:1 mixture of carbon monoxide and hydrogen gas and is called water gas because it is formed from steam and hot carbon in the following reaction: H2 O(g) + C(s) ⇌ H2(g) + CO(g). Methanol, a liquid fuel that could possibly replace gasoline, can be prepared from water gas and hydrogen at high temperature and pressure in the presence of a suitable catalyst.(a) Write the expression for the equilibrium constant (Kc) for the reversible reaction2H2(g) + CO(g) ⇌ CH3 OH(g)                                ΔH = −90.2 kJ(b) What will happen to the concentrations of H2, CO, and CH3OH at equilibrium if more H2 is added?(c) What will happen to the concentrations of H2, CO, and CH3OH at equilibrium if CO is removed?(d) What will happen to the concentrations of H2, CO, and CH3OH at equilibrium if CH3OH is added?(e) What will happen to the concentrations of H2, CO, and CH3OH at equilibrium if the temperature of the system is increased?(f) What will happen to the concentrations of H2, CO,…

A chemical engineer is studying the following reaction: HCH;CO,(aq)+CH,NH,(aq) → CH;CO,(aq)+CH,NH,(2q) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 1.6. The engineer charges ("fills") four reaction vessels with acetic acid and methylamine, and lets the reaction begin. She then measures the composition of the mixture inside each vessel from time to time. Her first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time she measures the compositions. reaction compound expected change in cor concentration concentration vessel HCH,CO, 0.96 M O T increase OI decrease O (no change) CH, NH, 0.88 M O f increase OI decrease O (no change) A CH,Co, 0.54 M O f increase OI decrease O (no change) CH,NH, 0.45 M O f increase OI decrease O (no change) HCH, CO, 0.88 M f increase OI decrease O (no change) CH,NH, 0.77 M O f increase OI decrease O (no change) B CH, Co, 1.09 M O increase OI…