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Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Please explain how to fill in table given provided information thanks

Transcribed Image Text:CELL POTENTIAL
Electrode system used
in cell
Zn (s) | Zn²+ (aq) || Cu²+
(aq) | Cu (s)
Zn (s) | Zn²+ (aq) || Fe³+
(aq) | Fe²+ (s) | graphite
Cu (s) | Cu²+ (aq) || Ag+
(aq) | Ag (s)
Zn (s) | Zn²+ (aq) || Ag+
(aq) | Ag (s)
Zn (s) | Zn²+ (aq) || 12 (s) |
1- (aq) | graphite
Fe2+ (s) | Fe³+ (aq) || Br₂
(1) | Br- (aq) | graphite
CI- (aq) | Cl₂ (g, 1 atm) || |
Br2 (1) Br- (aq) | graphite
Cell
Negative
Potential (V) Electrode
0.825 Zn
0.407 Zn
0.413 Cu
1.250 Zn
1.025 Zn
0.408 Fe
0.103 CI
Oxidation
Reaction
Zn (s)->
Zn²+ + 2e
Zn (s) ->
Zn²+ + 2e
Cu (s) ->
Cu²+ (aq) +
2e
Zn (s)->
Zn²+ + 2e
->
Zn (s)
Zn²+ + 2e
Fe²+ (s)->
Fe³+ + e
Cl- (aq) ->
Cl₂ (g, 1 atm)
Eº Reduction Eº
Oxida Reaction
tion
(M)
1.25
Cu²+ (aq)
+ 2e ->
Cu (s)
1.25 Fe³+ (aq)
-> Fe²+
(s)
0.413 Ag+ (aq) +
e -> Ag
(s)
1.25 Ag+ (aq) +
e
> Ag
(s)
1.25 12 (s) + e
0.538
-> 1- (aq)
0.843 Br2 (1) + e
-> Br-
(aq)
Br2 (1) –>
Br- (aq) +
e
Reduction
(M)
-0.425
-0.843
0.00
0.00
-0.225
-0.435
-0.435

Transcribed Image Text:264 Experiment 32 Voltaic Cell Measurements
A.2. Table of Electrode Potentials
In Table A.1, you should have a value for Ed or Exid for each of the electrode systems you have studied.
Remembering that for any electrode system, Ered =-E0
Eoxid, you can find the value for Ered for each system. List
those potentials in the left column of the table below, in order of decreasing (more negative) value.
Ereduction
Ag+,Ag
= 0.00 V)
Electrode reaction
in reduction
(Eº
=
Ereduction
H+,H₂
= 0.00 V)
The electrode potentials you have determined are based on setting Egt.Ag 0.00 V. The usual convention in
electrochemistry is to set EH¹,H₂ = 0.00 volts, under which conditions E
Ag+,Ag red
= +0.80 V. Convert from
one base to the other by adding 0.80 volts to each of the electrode potentials in the first column, and enter
these values in the third column of the table.
Why are the values of Ed on the two bases related to each other in such a simple way?
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