Chemistry
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10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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### Study Point Analysis: Lead-Tin Phase Diagram at 200°C

**Study Point A:**
- **Temperature:** 200°C (400°F)
- **Composition:** 40% Tin (Sn), 60% Lead (Pb)

**Questions:**

a. **Phases Present**
   - Determine which phases are present at this specific temperature and composition.

b. **Complete Composition of Each Phase**
   - Analyze each phase for its complete composition.

c. **Weight Amount of Each Phase**
   - Calculate the weight amount of each phase present.

d. **Maximum Solubility of Lead into Tin**
   - Identify the maximum solubility of lead in tin and at which temperature this occurs.

e. **Maximum Solubility of Tin into Lead**
   - Determine the maximum solubility of tin in lead and at which temperature this occurs.

f. **Eutectic Reaction and Composition**
   - Specify the complete eutectic reaction temperature and composition.

g. **Maximum Solubility of Tin into Lead at 200°F**
   - Calculate the maximum solubility of tin in lead at 200°F.

h. **Volume Fraction of Each Phase**
   - Calculate the volume fraction of each phase (\(\alpha\) and Liquid) with given densities:

   - \(\rho_{Sn} = 7.24 \text{ gr/cm}^3\)
   - \(\rho_{Pb} = 11.23 \text{ gr/cm}^3\)

### Diagram Explanation:

**Figure 9.8:**
- **Title:** The Lead-Tin Phase Diagram
- **Axes:**
  - X-axis: Composition (wt% Sn, from 0 to 100)
  - Y-axis: Temperature (°C, from 0 to 400)
  
- **Key Features:**
  - The diagram denotes boundaries for various phases: \(\alpha\) + L (liquid), \(\alpha\), and \(\beta + L\).
  - Eutectic point at approximately 183°C with a composition of about 61.9% Tin.
  - Indicates solid-liquid transformation regions and solid-state solubility limits.

**Diagram Annotations:**
- **Point A:** Represents a condition with 40% Sn and 60% Pb at 200°C.
- **Temperature Lines:** Indicate phase transitions, especially the eutectic transformation.

This graphical
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Transcribed Image Text:### Study Point Analysis: Lead-Tin Phase Diagram at 200°C **Study Point A:** - **Temperature:** 200°C (400°F) - **Composition:** 40% Tin (Sn), 60% Lead (Pb) **Questions:** a. **Phases Present** - Determine which phases are present at this specific temperature and composition. b. **Complete Composition of Each Phase** - Analyze each phase for its complete composition. c. **Weight Amount of Each Phase** - Calculate the weight amount of each phase present. d. **Maximum Solubility of Lead into Tin** - Identify the maximum solubility of lead in tin and at which temperature this occurs. e. **Maximum Solubility of Tin into Lead** - Determine the maximum solubility of tin in lead and at which temperature this occurs. f. **Eutectic Reaction and Composition** - Specify the complete eutectic reaction temperature and composition. g. **Maximum Solubility of Tin into Lead at 200°F** - Calculate the maximum solubility of tin in lead at 200°F. h. **Volume Fraction of Each Phase** - Calculate the volume fraction of each phase (\(\alpha\) and Liquid) with given densities: - \(\rho_{Sn} = 7.24 \text{ gr/cm}^3\) - \(\rho_{Pb} = 11.23 \text{ gr/cm}^3\) ### Diagram Explanation: **Figure 9.8:** - **Title:** The Lead-Tin Phase Diagram - **Axes:** - X-axis: Composition (wt% Sn, from 0 to 100) - Y-axis: Temperature (°C, from 0 to 400) - **Key Features:** - The diagram denotes boundaries for various phases: \(\alpha\) + L (liquid), \(\alpha\), and \(\beta + L\). - Eutectic point at approximately 183°C with a composition of about 61.9% Tin. - Indicates solid-liquid transformation regions and solid-state solubility limits. **Diagram Annotations:** - **Point A:** Represents a condition with 40% Sn and 60% Pb at 200°C. - **Temperature Lines:** Indicate phase transitions, especially the eutectic transformation. This graphical
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To determine the phase present at the point A (200°C) -40 % tin and 60 Pb. Also the complete composition of each phase and the weight composition of each phase at the given point is needed to be determined. 

 

 

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at 100C what is the maximum solubility (a) of Pb in Sn and (b) of Sn in Pb? The lead-tin phase diagram is shown in the animated figure

wt% Pb ?

wt% Sn ?

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at 100C what is the maximum solubility (a) of Pb in Sn and (b) of Sn in Pb? The lead-tin phase diagram is shown in the animated figure

wt% Pb ?

wt% Sn ?

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