Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- 4) A buffer solution is made from 135 mL of 0.395 M in HC2H3O2 and 115 mL 0.345 M NaC2H3O2 (the Ka of acetic acid is 1.79 x 10-5). a. Determine the pH of the initial buffer solution. b. What is the buffering range of this solution? c. What is the buffering capacity of this solution? d. What is the maximum volume of 2.00 M HCl solution you can add this buffer before it is no longer effective?arrow_forwardConsider how to prepare a buffer solution with pH = 2.97 (using one of the weak acid/conjugate base systems shown here) by combining 1.00 L of a 0.418-M solution of weak acid with 0.351 M potassium hydroxide. Weak Acid Conjugate Base Ka pKa HNO2 NO2- 4.5 x 10-4 3.35 HClO ClO- 3.5 x 10-8 7.46 HCN CN- 4.0 x 10-10 9.40 How many L of the potassium hydroxide solution would have to be added to the acid solution of your choice?arrow_forwardPart A: Calculating a Theoretical Titration Curve (Weak Acid – Strong Base) Consider the titration of 50.00 mL of 0.05 M acetic acid with 0.1 M NaOH. Calculate the pH of the resulting solution at the following points during the titration (given as volume of NaOH added). Volume NaOH pH of analyte 0.00 15.00 20.00 24.00 24.50 mL at equivalence point 40.00arrow_forward
- Calculate the pH of the following buffer solutions:1- 1.7 g/L of NH, and 5.35 g/L of NH,CI.2- 50 mL of I M CH COONa and I L 0.1 M CH COOH3- 50 mL of 1 M NaOH and I L 0.1 M CH.COOH.4- 10 mL 0.1 H,PO + 25 mL 0.1 NaOH5- 10 mL 0.1 HPO + 25 mL 0.1 Na PO6- A buffer solution pH=5.00 contains 0.01 M CH COOH.Calculate the concentration of sodium acetate it contains.7- What weight of NH,CI should be added to I L of 0.1 MNH, solution to get pH=9.00?arrow_forwardWhich of the following, if dissolved in 1.0 L of pure water, will produce a buffer solution? 0.1 mole HCL + 0.1 mole KCl 0.1 mole NaH2PO4 + 0.1 mole Na2HPO4 0.1 mole NaCl + 0.1 mole KCl 0.1 mole of H3O+ + 0.1 mole OH- I am guessing option 2, but need clarification please!arrow_forward10) An aqueous solution has [HC/HsO₂) = 0.100 M and (Ca(C7H5O2)2] = 0.200 M. K. = 6.3 × 105 for HC-H₂O₂. The solution volume is 5.00 L. What is the pH of the solution after 10.00 mL of 5.00 M NaOH is added?arrow_forward
- 1. calculate the pH of a solution obtained by mixing 30.4 mL of 0.03 M HCL with 31.4 mL of o.1 M HNO3 solution 2.A given weak acid has a pKa of 8.27. Calculate the percent ionized in 0.34 M of the weak acid. 3. Calculate the pH of 0.021 M Sr(OH )2 PLEASE DO ALL THREEarrow_forwardCalculate the pH of each of the following solutions a. 0.10 M propanoic acid, CH3CH2COOH, Ka = 1.3 x 10-5 b. 0.10 M sodium propanoate, NaCH3CH2COO. c. A mixture containing 0.10 M propanoic acid and 0.10 M sodium propanoate d. Calculate the pH after 0.020 mole of HCl is added to 1.00 L of a solution that contains 0.10 M propanoic acid and 0.10 M sodium propanoate e. Calculate the pH after 0.020 mole of NaOH is added to 1.00 L of a solution that contains 0.10 M propanoic acid and 0.10 M sodium propanoatearrow_forward5. A common buffer solution can be prepared by using ammonia and ammonium salts. The base equilibrium constant is 1.815×10-5. A student is preparing a pH buffer solution with 2.561 M NH3 solution and (NH4)2SO4 solid. Please answer the following questions. A. B. What is the best pH buffer range of the buffer solution that can be prepared by NH3 solution and (NH4)2SO4 solid? Please put down "1" if the answer is pH = 4.741 ± 1, please put down "2" if the answer is pH = 4.741 ± 10, please put down "3" if the answer is pH = 9.26 ± 1, please put down "4" if the answer is pH = 9.26 ± 10. Your answer follows. Assume that the addition of the solid will NOT change the volume, how many grams of is needed to prepare a pH = 8.66 buffer solution? The volume of the buffer solution is 250.0 mL. gramsarrow_forward
- Data: Mass of Sodium Acetate :4.0 g Volume of Sodium Acetate Solution: 100.00mL Acetic Acid Concentration (mass percent from label) :4.5% pH of Prepared Buffer Solutions Buffer Solution Acetic Acid; 4.5% Sodium Acetate Solution Recorded pH A 5.0 mL 5.0 mL 4.3 B 5.0 mL 1.0 mL 4.2 C 10.0 mL 1.0 mL 3.4 D 1.0 mL 10.0 mL 5.0 E 1.0 mL 5.0 mL 4.5 The answers must have the correct units and the correct number of significant figures 1. Sodium acetate moles __________________________ (molar mass = 82.0 g/mol) Molarity of sodium acetate = _______________________ Concentration of acetic acid (from bottle) = ____________ Molarity of acetic acid = ___________________________ (molar mass = 60.0 g/mol; density of the solution is 1.0 g/mL)arrow_forward8. Which of the following conjugate acid-base pair would you choose to prepare a buffer solution that has a pH of 4.20? A. HSO4-/SO42- (Ka = 1.2x10-²) B. C6H5COOH and C6H5COO-(Ka = 6.3 x 10-5) C. HCIO and CIO- (Ka = 3.5 x 10-8) D. HPO4-2 and P04-3 (Ka = 3.6 x 10-¹³) E. None of the choicesarrow_forwardAssuming equal concentrations of conjugate base and acid, which one of the following mixtures is the best choice for making a buffer solution with an optimum pH in the range of 3.1-3.5? O O O NaNO2/HNO2 (K₂ = 4.6 x 10-4) KCH3COO/CH3COOH (K₂ = 1.75 x 10-5) CH3NH2/CH3NH3CI (K₂ = 2.3 x 10-11) NaOCN/HOCN (K₂ = 2.0 x 10-4) NaNO3/HNO3 20arrow_forward
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