A. Say 0.0101 moles of gas in a car engine cylinder under a pressure of 608 kPa at 882 K expands adiabatically and irreversibly against 1 atm pressure. The Cv,m of the gas is 20.8 J/K/mol while Cp,m = 29.12 J/K/mol, so what is q, Vi, Tf, Pf, U, w, and H? B. Say 0.0101 moles of gas in a car engine cylinder at atmospheric pressure at 90 °C contracts adiabatically and reversibly until it is at 608 kPa pressure. The Cv,m of the gas is 20.8 J/K/mol while Cp,m = 29.12 J/K/mol, so what is q, Tf, U, w, and H? Hint: (Pi/Pf)= (Ti/Tf)^(CV+nR/nR)
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
A. Say 0.0101 moles of gas in a car engine cylinder under a pressure of 608 kPa at 882 K expands adiabatically and irreversibly against 1 atm pressure. The Cv,m of the gas is 20.8 J/K/mol while Cp,m = 29.12 J/K/mol, so what is q, Vi, Tf, Pf, U, w, and H?
B. Say 0.0101 moles of gas in a car engine cylinder at atmospheric pressure at 90 °C contracts
adiabatically and reversibly until it is at 608 kPa pressure. The Cv,m of the gas is 20.8 J/K/mol
while Cp,m = 29.12 J/K/mol, so what is q, Tf, U, w, and H?
Hint: (Pi/Pf)= (Ti/Tf)^(CV+nR/nR)
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