A vial is discovered in a loboratory refrigerator kabeled only as deconons, A moss spectrum is recorded and is shown below. Baesed on consideration of a-cleavages and Mclofferty rearrongements which of the deconones shown below was most likely in the vial? MASS SPECTRUM 100 80 20 0.0+ 120 160 Major frogment peaks are at m/z 43, 58, 71, 86, 113. Rel. ntensity

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A vial is discovered in a laboratory refrigerator labeled only as decanone. A mass
spectrum is recorded and is shown below. Based on consideration of a-cleavages and
McLafferty rearrangements which of the decanones shown below was most likely in the
vial?
MASS SPECTRUM
100
80 -
60
40
20
0.0
0.0
40
80
120
160
m/z
Major fragment peaks are at m/z 43, 58, 71, 86, 113.
Transcribed Image Text:A vial is discovered in a laboratory refrigerator labeled only as decanone. A mass spectrum is recorded and is shown below. Based on consideration of a-cleavages and McLafferty rearrangements which of the decanones shown below was most likely in the vial? MASS SPECTRUM 100 80 - 60 40 20 0.0 0.0 40 80 120 160 m/z Major fragment peaks are at m/z 43, 58, 71, 86, 113.
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