Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- The reaction H2(g) + I2(g) 2HI(g) has Kp = 45.9 at 763 K. A particular equilibrium mixture at 763 K contains HI at a pressure of 3.01 atm and H2 at a pressure of 2.62 atm. Calculate the equilibrium pressure of I2(g) in this mixture.arrow_forwardO KINETICS AND EQUILIBRIUM Using the small x approximation to solve equilibrium problems A chemist is studying the following equilibirum, which has the given equilibrium constant at a certain temperature: 2 NO(g) + Cl,(g) 2 NOCI(g) K,=2. x 107 He fills a reaction vessel at this temperature with 8.0 atm of nitrogen monoxide gas and 9.7 atm of chlorine gas. Use this data to answer the guestions in the table below. O yes Can you predict the equilibrium pressure of NOCI, using only the tools available to you within ALEKS? O no If you said yes, then enter the equilibrium pressure of NOCI at right. Round your answer to 1 significant digit. atm IIarrow_forwardThe equilibrium constant Kp for the reaction PC15(g) = PC13(g) + Cl₂(g) is 1.05 at 250°C. The reaction starts with a mixture of PC15, PC13, and Cl₂ at pressures 0.177 atm, 0.233 atm, and 0.161 atm, respectively, at 250°C. When the mixture comes to equilibrium at that temperature, which pressure(s) will have decreased? Cl₂ PC13 PC15arrow_forward
- Consider the equilibrium between SbCl5, SbCl3 and Cl₂. SbCl5(g) SbCl3(g) + Cl₂(g) K = 2.46x10-² at 530 K The reaction is allowed to reach equilibrium in a 7.30-L flask. At equilibrium, [SbCl5] = 0.430 M, [SbCl3] = 0.103 M and [Cl₂] = 0.103 M. (a) The equilibrium mixture is transferred to a 14.6-L flask. In which direction will the reaction proceed to reach equilibrium? (b) Calculate the new equilibrium concentrations that result when the equilibrium mixture is transferred to a 14.6-L flask. [SbCl5] = [SbCl3] = [Cl₂] |||| ΣΣΣarrow_forwardA tiny sample of an aqueous solution of two substances R and P is sketched below, as if it was under an imaginary microscope so powerful that individual molecules could be seen. (The water molecules are not shown.) R P R and P can interconvert. That is, R can turn into P, and P can turn back into R: R(aq) P(ag) K= The equilibrium constant K for this equilibrium is Predict the number of R and P molecules in this sample when the interconversion reaches equilibrium. number of R molecules: number of P molecules:| Check Privacy Center Accessibility Explanation 02022 McGraw Hill LLC. All Rights Reserved. Terms of Use /2arrow_forwardA tiny sample of an aqueous solution of two substances R and P is sketched below, as if it was under an imaginary microscope so powerful that individual molecules could be seen. (The water molecules are not shown.) R P R and P can interconvert. That is, R can turn into P, and P can turn back into R: R(aq)P(aq) 2 K 3 2 The equilibrium constant K for this equilibrium is Predict the number of R and P molecules in this sample when the interconversion reaches equilibrium. 3 number of R molecules: number of P molecules: Garrow_forward
- At 2516 °C the equilibrium constant for the reaction: 2 BrCl(g) Br₂(g) + Cl₂(g) is Kp = 0.863. If the initial pressure of BrCl is 0.00277 atm, what are the equilibrium partial pressures of BrCl, Br₂, and Cl₂? p(BrCl) = p(Br₂) = p(Cl₂) =arrow_forwardA chem ngineer is studying the following reaction: 4 HCl(g)+O,(g) – 2 H,0(g)+2Cl,(g) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.0040. The engineer charges ("fillsf) four reaction vessels with hydrogen chloride and oxygen, and lets the reaction begin. He then measures the co mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction compound pressure expected change in pressure vessel HCl 8.71 atm Ot increase O! decrease O (no change) 02 8.13 atm O t increase OI decrease O (no change) H,0 3.63 atm Ot increase OI decrease (no change) I decrease (no change) Cl, 1.91 atm ease I decrease (no change) 7,61 atm t increase HCI I decrease O (no change) 7,86 atm O f increase 0, I decrease O (no change) 4.18 atm t increase H,0 I decrease (no change) t increase 2.46 atm Cl, I decrease O (no…arrow_forwardA chemical engineer is studying the following reaction: H₂(g) + Cl₂(g) → 2 HCl(g) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.83. The engineer charges ("fills") three reaction vessels with hydrogen and chlorine, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction vessel A C compound H₂ Cl₂ HCI H₂ CL₂ HCI H₂ CL₂ HCI pressure 4.00 atm 1.97 atm 3.36 atm 4.27 atm 2.82 m 3.84 atm 1.81 atm 3.69 atm expected change in pressure 1 increase O decrease decrease Of increase Of increase Ⓒ↓ decrease Of increase O decrease decrease O1 increase Ot increase O decrease Of increase O decrease Of increase O decrease decrease Of increase O (no change) (no change) O(no change) (no change) (no change) (no change) (no change) (no…arrow_forward
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