General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN: 9781305580343
Author: Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher: Cengage Learning
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- What does “STP’ stand for? What conditions correspond to STP? What is the volume occupied by one mole of an ideal gas at STParrow_forwardButane gas, C4H10, is sold to campers as bottled fuel. Its density at 25C and 1.00 atm is 2.38 g/L. What volume of butane gas at 25C and 1.00 atm is required to heat one gallon of water (d=1.00g/mL) from 25C to 98C ? The reaction for the combustion of butane (H f =125.6kJ/mol) is C4H10(g)+132 O2(g)4CO2(g)+5H2O(g)arrow_forwardExplain why the plot of PV for CO2 differs from that of an ideal gas.arrow_forward
- 62 Ammonium dinitramide (ADN), NH4N(NO2)2, was considered as a possible replacement for aluminium chloride as the oxidizer in the solid fuel booster rockets used to launch the space shuttle. When detonated by a spark, AND rapidly decomposes to produce a gaseous mixture of N2,O2, and H2O. (This is not a combustion reaction. The ADN is the only reactant.) The reaction releases a lot of heat, so the gases are initially formed at high temperature and pressure. The thrust of the rocket results mainly from the expansion of this gas mixture. Suppose a 2.3-kg sample of ADN is denoted and decomposes completely to give N2,O2, and H2O. If the resulting gas mixture expands until it reaches a temperature of 100°C and a pressure of 1.00 atm, what volume will it occupy? Is your answer consistent with the proposed use of ADN as a rocket fuel?arrow_forwardOne of the components of polluted air is NO. It is formed in the high-temperature environment of internal combustion engines by the following reaction: N2(g)+O2(g)2NO(g)H=180KJ Why are high temperatures needed to convert N2 and O2 to NO?arrow_forward105 The decomposition of mercury(II) thiocyanate produces an odd brown snake-like mass that is so unusual the process was once used in fireworks displays. There are actually several reactions that take place when the solid Hg(SCN)2 is ignited: 2Hg(SCN)2(s)2HgS(s)+CS2(s)+C3N4(s)CS2(s)+3O2(g)CO2(g)+2SO2(g)2C3N4(s)3(CN)2(g)+N2(g)HgS(s)+O2(g)Hg(l)+SO2(g) A 42.4-g sample of Hg(SCN)2 is placed into a 2.4-L vessel at 21°C. The vessel also contains air at a pressure of 758 torr. The container is sealed and the mixture is ignited, causing the reaction sequence above to occur. Once the reaction is complete, the container is cooled back to the original temperature of 21°C. (a) Without doing numerical calculations, predict whether the final pressure in the vessel will be greater than, less than, or equal to the initial pressure. Explain your answer. (b) Calculate the final pressure and compare your result with your prediction. (Assume that the mole fraction of O2 in air is 0.21.)arrow_forward
- You heat 1.000 quart of water from 25.0C to its normal boiling point by burning a quantity of methane gas, CH4. What volume of methane at 23.0C and 745 mmHg would you require to heat this quantity of water, assuming that the methane is completely burned? The products are liquid water and gaseous carbon dioxide.arrow_forwardPropane, C3H8, is a hydrocarbon that is commonly used as a fuel. (a) Write a balanced equation for the complete combustion of propane gas. (b) Calculate the volume of air at 25 C and 1.00 atmosphere that is needed to completely combust 25.0 grams of propane. Assume that air is 21.0 percent O2 by volume. (Hint: we will see how to do this calculation in a later chapter on gasesfor now use the information that 1.00 L of air at 25 C and 1.00 atm contains 0.275 g of 2 per liter.) (c) The heat of combustion of propane is 2,219.2 kJ/mol. Calculate the heat of formation, Hf of propane given that Hf of H2O(l)=285.8 kJ/mol and Hf of CO2(g)=393.5 kJ/mol. (d) Assuming that all of the heat released in burning 25.0 grams of propane is transferred to 4.00 kilograms of water, calculate the increase in temperature of the water.arrow_forwardUrea (H2NCONH2) is used extensively as a nitrogen source in fertilizers. It is produced commercially from the reaction of ammonia and carbon dioxide: 2NH3(g)+CO2(g)PressureHeatH2NCONH2(s)+H2O(g) Ammonia gas at 223C and 90. atm flows into a reactor at a rate of 500. L/min. Carbon dioxide at 223C and 45 atm flows into the reactor at a rate of 600. L/min. What mass of urea is produced per minute by this reaction assuming 100% yield?arrow_forward
- Which of the following statement about coal gasification is INCORRECT?A. The synthesis gas is CH4.B. It produces liquid coal under high pressure and temperature.C. It relieves the stress from oil and gas supply.D. It is a type of non-renewable energy.E. The first step is called steam reforming.arrow_forwardPlease show workarrow_forwardAcetylene gas reacts with oxygen and burns at high temperature in an acetylene torch. a. Write the balanced equation for the complete combustion of acetylene. b. How many grams of O2 are needed to react with 8.5 L acetylene at STP? (hint 1 mol O2 (STP)=22.4 L of O2) c. How many liters of CO2 (at STP) are produced when 30.0 g of acetylene undergoes combustion? (hint 1 mol CO2 (STP)=22.4 L of CO2)arrow_forward
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