Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- (4a) The following initial rate data are for the reduction of nitric oxide with hydrogen:2 NO + 2 H2N2 + 2 H2O Experiment [NO]o, M [H2]o, M Initial Rate, M s-1 1 0.438 0.289 7.93×10-2 2 0.876 0.289 0.317 3 0.438 0.578 0.159 4 0.876 0.578 0.634 Complete the rate law for this reaction in the box below. Use the form k[A]m[B]n , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n. Rate = From these data, the rate constant is ____________ M-2s-1. (4b) The following initial rate data are for the reaction of ammonium ion with nitrite ion in aqueous solution:NH4+ + NO2- N2 + 2 H2O Experiment [NH4+]o, M [NO2-]o, M Initial Rate, Ms-1 1 0.710 0.152 3.38×10-5 2 0.710 0.303 6.73×10-5 3 1.42 0.152 6.76×10-5 4 1.42 0.303 1.35×10-4 Complete the rate law for this reaction in the box below. Use the form k[A]m[B]n , where '1' is understood for m or n and concentrations taken to the zero power do not…arrow_forwardFor the reaction 2 N,O5(2) 4 NO2(2) + O22) , the following data were collected: time (min) [N,O5] (mol/L) 1.24 x 10-2 10 0.92 x 10-2 20 0.68 x 10-2 30 0.50 x 10-2 40 0.37 x 10-2 50 0.28 x 10-2 70 0.15 x 10-2 The order of this reaction in N,Os is The order of this reaction in N,O5 is a. b. 1 C. 2 d. 3. e. 0.5arrow_forwardThe rate constant of a certain reaction is known to obey the Arrhenius equation, and to have an activation energy E=52.0 kJ/mol. If the rate constant of this -1 -1 reaction is 1.7 × 10+ M's at 197.0 °C, what will the rate constant be at 168.0 °C? Round your answer to 2 significant digits. k = □M -1 5 ? 0 xno 圖□ □ □arrow_forward
- There are several factors that affect the rate constant of a reaction. These factors include temperature, Templetes activation energy, steric factors (orientation), and also collision frequency, which changes with concentration and phase. All the factors that affect the rate constant can be summarized in an equation called the Arrhenius equation: Part A k= Ae/r where k is the rate constant, A is the frequency factor, E, is the activation energy, R= 8.314 J/(mol - K) is the universal gas constant, and T is the absolute temperature. A certain reaction has an activation energy of 70.0 kJ/mol and a frequency factor of A1 = 6.10x1012 M-'s 1. What is the rate constant, k, of this reaction at 29.0 °C ? Express your answer with the appropriate units. Indicate the multiplication of units explicitly either with a multiplication dot (asterisk) or a dash. > View Available Hint(s) Tempjetes Symbols undo redo test keyboard shortouts Help k= 1.61 m's-1 Submit Prevlous Anawere X Incorrect; Try Again;…arrow_forwardThe rate constant of a certain reaction is known to obey the Arrhenius equation, and to have an activation energy E = 14.0 kJ/mol. If the rate constant of a -1 this reaction is 2.3 × 10° Ms at 4.0 °C, what will the rate constant be at 63.0 °C? Round your answer to 2 significant digits. -1 k = M 181 olo Ararrow_forwardThe following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution: Experiment 1 2 3 4 3+ AsO3³ + 2Ce¹+ + H₂O → AsO4³ + 2Ce³+ + 2H+ Rate = k = [ASO3³] [Ce¹+] M M 0.0311 0.0622 0.0311 0.0622 M-2.s I Complete the rate law for this reaction in the box below. Use the form k[A] [B]", where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n. -1 0.145 0.145 0.290 0.290 Initial Rate, M.s-1 S 0.000345 0.000690 0.00138 0.00276arrow_forward
- 8arrow_forwardPlease provide the step by step solution for the question attached. Graphics must be included. Please make sure the graphics are visible.arrow_forwardIf the y-axis of the graph changes to “volume of hydrogen / cm3 ”, sketch this rate curve. What will be the effect on the reaction rate if the concentration of HCl changes from 0.1 M to 0.2 M? Explainarrow_forward
- A reaction profile (not to scale!) for the reaction СН,Br + OH —С,H;ОН + Br →C¿H5OH + Br is shown below: Е (kJ) 90 C2H5BR + OH" 71 C2H5OH + Br* Reaction Coordinate This reaction is (exothermic,endothermic) The value of the activation energy for this reaction is kJ and the value of AE is kJ.arrow_forwardUsing the data in the table, calculate the rate constant of Trial [A] (M) [B] (M) Rate (M/s) this reaction. 1 0.260 0.280 0.0119 A + B → C+ D 2 0.260 0.784 0.0933 3 0.312 0.280 0.0143 Units k = M-²s-1 M-'s-! M-s-!arrow_forward152. Experimental data for the reaction 2NO, (e) + Fa(g) - 2NO,F(g) are given in the table below. NO: (M)Fa) (M) Initial rate (M/s) Part B Jation Calculate the value of the rate constant, k 0.100 0.100 0.026 Express your answer in liters per mole per second to three significant figures. 10.200 0.100 0.051 View Available Hint(s) 0.200 0.200 0.400 0.103 0.400 0.411arrow_forward
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