A process for ethanol synthesis has been developed and the ethylene hydration operating conditions have been optimized in order to reduce production costs. Ethanol is manufactured by reacting ethylene with steam at 150°C (423.15 K). The reaction takes place in a gas phase and the formation of the ethanol is an exothermic process and assume as ideal gases. C2H4(g) +H20(g) → C2H5OH(g) Your classmate claims that the equilibrium constant decreases as the temperature decreases. Evaluate the effect of reducing the temperature to 100 °C whether this observation make sense. Support your answer with the necessary calculations.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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A process for ethanol synthesis has been developed and the ethylene hydration operating conditions have been optimized in order to reduce production costs. Ethanol is manufactured by reacting ethylene with steam at 150°C (423.15 K). The reaction takes place in a gas phase and the formation of the ethanol is an exothermic process and assume as ideal gases.


C2H4(g) +H20(g) → C2H5OH(g)


Your classmate claims that the equilibrium constant decreases as the temperature decreases. Evaluate the effect of reducing the temperature to 100 °C whether this observation make sense. Support your answer with the necessary calculations.


Available information for the calculation are as follows:(Refer attachment)

AH°298 (J/mol)
-45,792
AG°298 (J/mol)
-8,378
ΔΑ
ΔΒ
AC
ΔD
-1.376
4.157X10-3
-1.610X10-6
-1.210X10*4
Transcribed Image Text:AH°298 (J/mol) -45,792 AG°298 (J/mol) -8,378 ΔΑ ΔΒ AC ΔD -1.376 4.157X10-3 -1.610X10-6 -1.210X10*4
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