Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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2. Methane gas is combusted with air, supplied in 25% excess. Calculate the
maximum attainable temperature in the combustion chamber. The reacting gases
are supplied at 25°C. Air is taken to be 21% O, and 79% N.
The chemical reaction is,
CH, + 20, = CO, + 2H,0,
!!
Set the reference temperature to be 298 K. Data are available at this temperature
and it is convenient since the reactants are supplied at this temperature.
AHO, = 2AH°, (H,O) + AH°, (CO,) - AH°, (CH.)
74.873)
= 2x -241.827 + -393.505 - (-
= -802.286 kJ/mol
Take the energy balance to be based on 1 mole of the reaction as written. Then
AH°, - -802.286 kJ = -802,286 J.
The heat capacity data are tabulated below.
Cp = a +bX 10T +cX 10/ T + dX 10 T /mol K
a
CH.
2.731
96.3
5.9
-26.836
29.431
4.19
-2.858
-0.385
Co,
22.226
56.2
0.105
-22.518
33.568
-4.201
14.761
N2
29.192
-1.121
3.092
Calculate the T, (adiabatic temperature).
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Transcribed Image Text:2. Methane gas is combusted with air, supplied in 25% excess. Calculate the maximum attainable temperature in the combustion chamber. The reacting gases are supplied at 25°C. Air is taken to be 21% O, and 79% N. The chemical reaction is, CH, + 20, = CO, + 2H,0, !! Set the reference temperature to be 298 K. Data are available at this temperature and it is convenient since the reactants are supplied at this temperature. AHO, = 2AH°, (H,O) + AH°, (CO,) - AH°, (CH.) 74.873) = 2x -241.827 + -393.505 - (- = -802.286 kJ/mol Take the energy balance to be based on 1 mole of the reaction as written. Then AH°, - -802.286 kJ = -802,286 J. The heat capacity data are tabulated below. Cp = a +bX 10T +cX 10/ T + dX 10 T /mol K a CH. 2.731 96.3 5.9 -26.836 29.431 4.19 -2.858 -0.385 Co, 22.226 56.2 0.105 -22.518 33.568 -4.201 14.761 N2 29.192 -1.121 3.092 Calculate the T, (adiabatic temperature).
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