Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- In this lab, you will determine the vapour pressure (P) of water at various temperatures and use this data to find its enthalpy of vaporization (AvapH). More generally, for an unknown liquid: if a plot of In P vs. 1/T gives a slope of -8038 K, what is its AvapH in kl/mol? Do not worry about how realistic the value is. Assume R = 8.314 J mol- K-.arrow_forwardşvurular Posta Gönderileri Place a piece of copper in 0 Word ik: Her şey hazır 19° Gözden Geçir Görünüm Yardım When 50 g of phenol is mixed with 50 g of water at 20°C, two phases are formed. from phases one contains 8% phenol by mass and the other contains 72% phenol. The mass of each phase and this Find the masses of the components in the phases. Ne yapmak istediğinizi söyleyin (Ctrl)arrow_forward2-E, A liquid mixture of 30 mol benzene, 30 mol toluene, and 40 mol water initially at 70°C and 101.3 kPa total pressure is heated slowly at a constant pressure of 101.3 kPa to 90°C. The vapor generated stays in contact with the remaining liquid. Assuming equilibrium between phases at all times, estimate (a) the temperature at which vaporization begins, (b) the composition of the first vapor. (c) the temperature at which vaporization is complete, and (d) the composition of the last liquid. Note: Water is essentially totally immiscible with benzene and toluene. Each liquid phase contributes to the total vapor pressure. Over the temperature range involved, the vapor pressure of benzene is 2.60 times that of toluene, and the vapor pressure of water is 1.23 times that of toluene. Vapor pressure of water is: T. °C 70 72 74 76 78 80 82 84 86 88 90 P, kPa 31.2 34.0 36.9 40.1 43.6 47.3 51.3 55.6 60.1 64.9 70.1arrow_forward
- In the determination of molar mass of an unknown substance by ebullioscopic constant, 30 mL of acetone (C3H6O) was placed in a test tube with thermometer and glass tubing and subjected to water bath. Upon boiling, the temperature reads 56 degC. For the boiling point of unknown-acetone solution, you prepared the solution by mixing 1.60 g of unknown solute in the 30 mL acetone and subjected it again to water bath. The boiling temperature of the solution is 56.68 degC. The density of acetone = 0.9849 g/mL and the Kb of acetone = 1.67 degC/kg. How many moles of solute is present in the solution? Molality of the solution?arrow_forward-- ) AHyap ( (T2[K] _T[K] sat In Psat R Calculate the latent heat of vaporization by using the vapor pressures at T1 = 7.6 °C and T2 = 15.4 °C. Use the Clausius-Clapeyron equation to estimate the vapor pressure of benzene at 42.4 °C. Compare the values determined by Clausius-Clapeyron equation and Antoine equation. Antoine Equation for benzene: 2726.81 In Psat [kPa] = 13.7819 T[°C] + 217.572arrow_forward6. You have collected a tissue specimen that you would like to preserve by freeze drying (Dr. Cahill does this!!) To ensure the integrity of the specimen, the temperature should not exceed -5.00°C. The vapour pressure of ice at 273.16 K is 624 Pa. What is the maximum pressure at which the freeze drying can be carried out? AHfuzion=6010 J mol¹ and 4Hvaporization=40656 J mol-¹arrow_forward
- This question deals with the vapourization of acetone: CH,COCH,() - CH,COCH,(g) The boiling point of acetone is 329.3 Kand the enthalpy of vaporization, AvapH = 29.07 kJ mol.arrow_forwardIf a mixture is A + B where A = 10% and B = 90%. The enthalpy of vaporization of A = 33.9 kj/mol and pure A has boiling point of 375K.Calculate the boiling temperature of the mixture. Please explain the answer so it would make sense. I made a mistake of flipping the T pure and T solution so I got the wrong answer.arrow_forwardEstimate the freezing point (solidification temperature) of benzene at a pressure of 115 bar given that the enthalpy of fusion (AH,jus) of benzene is 9.94 kJ/mol. The corresponding densities of liquid and frozen benzene are 876 kg/m? and 894 kg/m? respectively.arrow_forward
- The vaporization enthalpy of the pure substance F at 1 bar and 300 K is 25 kJ/mol. Determine the change in the vaporization temperature of 3 moles of F caused by 0.2 moles of a solute.arrow_forwardOn single-component phase diagrams, the phase rule is given by f= 3 - p. This equation means that if f = 1, the region containing the indicated phases is a point. True Falsearrow_forwardAt 80°C an unknown solute dissolves in benzene to form a solution containing 1.25% weight of the solute. The vapour pressure of the solution is 752.4 mmHg and its boiling point is 80.25°C compared to the normal boiling point of benzene which is 80.00°C. Determine the molecular weight of the solute assuming it is non-volatile.arrow_forward
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