A chemist titrates 140.0 mL of a 0.4430 M hydrochloric acid (HCI) solution with 0.4963 M NaOH solution at 25 °C. Calculate the pH at equivalence. Round your answer to 2 decimal places. Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of NaOH solution added. PH =0 × 9

A chemist titrates 140.0 mL of a 0.4430 M hydrochloric acid (HCI) solution with 0.4963 M NaOH solution at 25 °C. Calculate the pH at equivalence. Round your answer to 2 decimal places. Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of NaOH solution added. PH =0 × 9

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter14: Equilibria In Acid-base Solutions

Section: Chapter Questions

Problem 50QAP: Morphine, C17H19O3N, is a weak base (K b =7.4107). Consider its titration with hydrochloric acid. In...

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Phenol, C6H5OH, is a weak organic acid. Suppose 0.515 g of the compound is dissolved in enough water to make 125 mL of solution. The resulting solution is titrated with 0.123 M NaOH. C6H5OH(aq) + OH(aq) C6H5O(aq) + H2O() (a) What is the pH of the original solution of phenol? (b) What are the concentrations of all of the following ions at the equivalence point: Na+, H3O+, OH, and C6H5O? (c) What is the pH of the solution at the equivalence point?
Consider all acid-base indicators discussed in this chapter. Which of these indicators would be suitable for the titration of each of these? (a) NaOH with HClO4 (b) acetic acid with KOH (c) NH3 solution with HBr (d) KOH with HNO3 Explain your choices.
A student intends to titrate a solution of a weak monoprotic acid with a sodium hydroxide solution but reverses the two solutions and places the weak acid solution in the buret. After 23.75 mL of the weak acid solution has been added to 50.0 mL of the 0.100 M NaOH solution, the pH of the resulting solution is 10.50. Calculate the original concentration of the solution of weak acid.
A solution made up of 1.0 M NH3 and 0.50 M (NH4)2SO4 has a pH of 9.26. a Write the net ionic equation that represents the reaction of this solution with a strong acid. b Write the net ionic equation that represents the reaction of this solution with a strong base. c To 100. mL of this solution, 10.0 mL of 1.00 M HCl is added. How many moles of NH3 and NH4+ are present in the reaction system before and after the addition of the HCl? What is the pH of the resulting solution? d Why did the pH change only slightly upon the addition of HCl?
You are given the following acidbase titration data, where each point on the graph represents the pH after adding a given volume of titrant (the substance being added during the titration). a What substance is being titrated, a strong acid, strong base, weak acid, or weak base? b What is the pH at the equivalence point of the tiration? c What indicator might you use to perform this titration? Explain.
Three students titrate different samples of the same solution of HCI to obtain its molarity. Below are their data. Student A: 20.00mLHCl+20.00mLH2O 0.100 M NaOH used to titrate to the equivalence point Student B: 20.00mLHCl+40.00mLH2O 0.100 M NaOH used to titrate to the equivalence point Student C: 20.00mLHCl+20.00mLH2O 0.100 M Ba(OH)2 used to titrate to the equivalence point. All the students calculated the molarities correctly. Which (if any) of the following statements are true? (a) The molarity calculated by A is half that calculated by B. (b) The molarity calculated by A is equal to that calculated by C. (c) The molarity calculated by B is twice that calculated by C. (d) The molarity calculated by A is twice that calculated by B. (e) The molarity calculated by A is equal to that calculated by B.
Consider the nanoscale-level representations for Question 110 of the titration of the aqueous weak acid HX with aqueous NaOH, the titrant. Water molecules and Na+ ions are omitted for clarity. Which diagram corresponds to the situation: After a very small volume of titrant has been added to the initial HX solution? When enough titrant has been added to take the solution just past the equivalence point? Halfway to the equivalence point? At the equivalence point? Nanoscale representations for Question 110.
Morphine, C17H19O3N, is a weak base (K b =7.4107). Consider its titration with hydrochloric acid. In the titration, 50.0 mL of a 0.1500 M solution of morphine is titrated with 0.1045 M HCl. (a) Write a balanced net ionic equation for the reaction that takes place during titration. (b) What are the species present at the equivalence point? (c) What volume of hydrochloric acid is required to reach the equivalence point? (d) What is the pH of the solution before any HCl is added? (e) What is the pH of the solution halfway to the equivalence point? (f) What is the pH of the solution at the equivalence point?
A quantity of 0.15 M hydrochloric acid is added to a solution containing 0.10 mol of sodium acetate. Some of the sodium acetate is converted to acetic acid, resulting in a final volume of 650 mL of solution. The pH of the final solution is 4.56. a What is the molar concentration of the acetic acid? b How many milliliters of hydrochloric acid were added to the original solution? c What was the original concentration of the sodium acetate?
consider the titration of 50.0 mL of 0.10 M acetic acid with NaOH. drag and drop each amount of NaOH added (to the acetic acid) Into the appropriate resulting pH. In other words, determine the pH of the final solution after each volume of NaOH has been added. Will the resulting solutions be acidic, basic, or neutral? Consider the stration of 50.0 ml of 0.10 M acetic acid (HC₂H₂O₂. K, -18 x 10) with NaOH. Drag and drop each amount of NaOH added to the acetic acid) into the appropriate resulting pH. In other words determine the pH of the final solution after each volume of NaOH has been added. Will the resulting solution be acidic, basic, or neutra? Acidic Neutral Basic Drag and drop your selection from the following list to complete the answer 25.0 mL (total) of 0.10 M NaOH has been added (the halfway point) 50.0 mL. (total) of 0.10 M NaOH has been added (the equivalence point) 10.0 mL (total) of 0.10 M NaOH has been added 60.0 mL (total) of 0.10 M NaOll has been added No NaOH has been…
Consider the following information to answer the questions below. A volume of 10.00 mL of 0.100 M acetic acid (HC2H3O2) is titrated with 0.148 M sodium hydroxide solution. Given the chemical equation below. Calculate the volume (in milliliters) of NaOH needed to reach the equivalence point of the titration. HC2H3O2(aq) + NaOH(aq) -> H2O (l) + NaC2H3O2(aq)
A 12.0 mL sample of NH3 is titrated with 0.225 M HCI (aq). It takes 9.50 mL of HCI (aq) to reach the equivalence point. Answer the following questions to three significant figures. The pk, for ammonia (NH3) is 4.75. What is the concentration of NH3 in the original solution? Enter a value accurate to three significant figures. Number M What is the pH at the equivalence point? Enter a value accurate to three significant figures. Number

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