Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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A chemical engineer is studying the following reaction:
4 HCl(g)+O2(g) → 2 H2O(g)+2Cl,(9)
At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.22.
The engineer charges ("fills") four reaction vessels with hydrogen chloride and oxygen, and lets the reaction begin. He then measures the composition of the
mixture inside each vessel from time to time. His first set of measurements are shown in the table below.
Predict the changes in the compositions the engineer should expect next time he measures the compositions.
reaction
compound
pressure
expected change in pressure
vessel
HCl
4.88 atm
↑ increase
O Į decrease
(no change)
02
8.21 atm
increase
O I decrease
(no change)
A
H,O
5.94 atm
O ↑ increase
O I decrease
(no change)
Cl,
5.44 atm
increase
O I decrease
(no change)
HCl
6.03 atm
O ↑ increase
O I decrease
(no change)
7.78 atm
O ↑ increase
Į decrease
(no change)
В
H,O
4.37 atm
O ↑ increase
O I decrease
(no change)
Cl,
3.93 atm
O ↑ increase
O I decrease
(no change)
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Transcribed Image Text:A chemical engineer is studying the following reaction: 4 HCl(g)+O2(g) → 2 H2O(g)+2Cl,(9) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.22. The engineer charges ("fills") four reaction vessels with hydrogen chloride and oxygen, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction compound pressure expected change in pressure vessel HCl 4.88 atm ↑ increase O Į decrease (no change) 02 8.21 atm increase O I decrease (no change) A H,O 5.94 atm O ↑ increase O I decrease (no change) Cl, 5.44 atm increase O I decrease (no change) HCl 6.03 atm O ↑ increase O I decrease (no change) 7.78 atm O ↑ increase Į decrease (no change) В H,O 4.37 atm O ↑ increase O I decrease (no change) Cl, 3.93 atm O ↑ increase O I decrease (no change)
HCl
2.73 atm
O ↑ increase
O Į decrease
(no change)
02
6.96 atm
O ↑ increase
O I decrease
(no change)
C
H,0
6.01 atm
O ↑ increase
Į decrease
(no change)
Cl,
5.57 atm
O ↑ increase
O I decrease
(no change)
expand button
Transcribed Image Text:HCl 2.73 atm O ↑ increase O Į decrease (no change) 02 6.96 atm O ↑ increase O I decrease (no change) C H,0 6.01 atm O ↑ increase Į decrease (no change) Cl, 5.57 atm O ↑ increase O I decrease (no change)
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