A binary mixture of components M and N forms an azeotrope at 120°C and liquid phase mole fraction of component 1 is x, = 0.3. The liquid phase non-ideality is given by In 7, = Ax ,Iny, = Ax² . Here, 7,,% are the activity coefficients and x,.x, are the liquid phase mole fractions. The fugacity coefficients of both the components at azeotropic composition is 0.7. Saturated vapor pressure at 120°C is, P" = 60 bar P = 30 bar Give total pressure for azeotropic system. a) 48 bar b) 38 bar c) 45 bar d) 56 bar

Introduction to Chemical Engineering Thermodynamics
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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A binary mixture of components M and N forms an azeotrope at 120°C and liquid phase
mole fraction of component 1 is x, = 0.3. The liquid phase non-ideality is given by
In 7, = Ax; ,Iny, = Ax¡ . Here, 7,,7 are the activity coefficients and x,x, are the liquid
phase mole fractions. The fugacity coefficients of both the components at azeotropic
composition is 0.7.
Saturated vapor pressure at 120°C is,
P = 60 bar
Pat = 30 bar
Give total pressure for azeotropic system.
a) 48 bar
b) 38 bar
c) 45 bar
d) 56 bar
Transcribed Image Text:A binary mixture of components M and N forms an azeotrope at 120°C and liquid phase mole fraction of component 1 is x, = 0.3. The liquid phase non-ideality is given by In 7, = Ax; ,Iny, = Ax¡ . Here, 7,,7 are the activity coefficients and x,x, are the liquid phase mole fractions. The fugacity coefficients of both the components at azeotropic composition is 0.7. Saturated vapor pressure at 120°C is, P = 60 bar Pat = 30 bar Give total pressure for azeotropic system. a) 48 bar b) 38 bar c) 45 bar d) 56 bar
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