Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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- SKIP THIS IF YOU ALREADY ANSWERED THIS. I WILL ONLY UPVOTE IF IT IS TYPEWRITTEN. FOLLOW THE INSTRUCTIONS AND DO IT COMPLETELY. DOWNVOTE IF YOU ANSWERED THIS AGAIN. THANK YOUarrow_forwardComplete the property table for water below. Use only the Thermodynamic Property Table for Water referring to the Smith, Van Ness and Abbot Thermodynamics textbook. P [kPa] V [m³/kg] H[ kJ/kg] T[°C] Phase Description X 500 Saturated liquid 171 2044.5 300 0.8 Note that x refers to the "quality" or the mass fraction of the water in vapor phase. If the system is composed of pure liquid water, x = 0. If the system is composed of pure gaseous steam, x = 1. The volume of a liquid/vapor system can be determined using the following equation. V = Vj + x(Vg-Vj) V - volume of saturated liquid water Va - volume of saturated gaseous steam Similar calculation can be done for other properties such as internal energy, entropy, and enthalpy. H = HỊ + x(Hg-H) Under phase description, indicate whether the system is composed of saturated liquid, saturated vapor, superheated vapor, or liquid-vapor mixture. Also note that when pressure is given, it is more advisable to use the Superheated Steam Table than…arrow_forward(a)Using the compressibility chart, determine the compression factor (Z). Express your final answers in 3 significant figures (b)What would be the corresponding state of carbon dioxide? (Pc = 72.9 atm, Tc = 304.2 K) T (K) 200 P (atm) Tс (К) Pc (atm) Gas Argon 23.0 150.7 48.0 1.1 1.0 T- 2.00 0.9 I=1.50 0.8 Tx =1.30 0.7 to 0.6 T=1.20 0.5 T-1.10 0.4 Legend: X Methane O Ethylene A Ethane O Propane O n-Butane Iso-pentane • n-Heptane A Nitrogen T =1.00 0.3 Carbon dioxide Water 0.2 Average curve based on data on hydrocarbons 0.1 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0 Reduced pressure P x of xarrow_forward
- Imagearrow_forwardSolve the following questions related to fugacity of a liquid. Assume that liquid is incompressible and thus the 1 molar volume of the liquid is constant. (You may assume that Psat is low enough that sat for all parts of this = problem. You will also need to look up or calculate the molar volume of water.) b) Calculate the fugacity and the fugacity coefficient of liquid water at 100°C and 1000 bar.arrow_forwardCalculate the fugacity of dry ice (CO₂ ice) at the triple point (T=216.55 °K, P-5.12673 bar). Assume that the thermal properties of the vapor phase of carbon dioxide are described by the Peng-Robinson equation of state. Express your result in bar and and round your numerical answer to one decimal digit.arrow_forward
- Sketch very roughly the phase diagrams for water and carbon dioxide and use them to answer this question: at a pressure of X atmospheres and a temperature Y degrees Kelvin,what is the phase of water, and what is the phase of carbon dioxide Y=9.43 X=943arrow_forwardSolve the following questions related to fugacity of a liquid. Assume that liquid is incompressible and thus the = 1 molar volume of the liquid is constant. (You may assume that Psat is low enough that sat for all parts of this problem. You will also need to look up or calculate the molar volume of water.) You are given a container partially filled with water at 25°C. You then proceed to pump all of the air out of the container, leaving a pool of water at the bottom, and a vacuum (P=0) at the top (see first panel in figure below). You then turn off the pump and seal the container. You wait a short while and the water in the bottom starts to evaporate (see second panel) until it achieves phase equilibrium (see third panel). Assuming no change in temperature and no significant change in volume of the water, what is the pressure in the box? (Hint: you must balance fugacity between the liquid and vapor phases. You may also assume the vapor phase is an ideal gas, and the liquid is an ideal…arrow_forward
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