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- (a) An ideal gas occupies a volume of 1.0 cm3 at 20.C and atmospheric pressure. Determine the number of molecules of gas in the container, (b) If the pressure of the 1.0-cm3 volume is reduced to 1.0 1011 Pa (an extremely good vacuum) while the temperature remains constant, how many moles of gas remain in the container?(a) An ideal gas occupies a volume of 1.0 cm3 at 20.C and atmospheric pressure. Determine the number of molecules of gas in the container, (b) If the pressure of the 1.0-cm3 volume is reduced to 1.0 1011 Pa (an extremely good vacuum) while the temperature remains constant, how many moles of gas remain in the container?(a) Show that the density of an ideal gas occupying a volume V is given by = PM/KT, where M is the molar mass. (b) Determine the density of oxygen gas at atmospheric pressure and 20.0C.
- A vertical cylinder of cross-sectional area A is fitted with a tight-fitting, frictionless piston of mass m (Fig. P16.56). The piston is not restricted in its motion in any way and is supported by the gas at pressure P below it. Atmospheric pressure is P0. We wish to find die height h in Figure P16.56. (a) What analysis model is appropriate to describe the piston? (b) Write an appropriate force equation for the piston from this analysis model in terms of P, P0, m, A, and g. (c) Suppose n moles of an ideal gas are in the cylinder at a temperature of T. Substitute for P in your answer to part (b) to find the height h of the piston above the bottom of the cylinder.A sealed cubical container 20.0 cm on a side contains a gas with three times Avogadros number of neon atoms at a temperature of 20.0C. (a) Find the internal energy of the gas. (b) Find the total translational kinetic energy of the gas. (c) Calculate the average kinetic energy per atom, (d) Use Equation 10.13 to calculate the gas pressure. (e) Calculate the gas pressure using the ideal gas law (Eq. 10.8).On a hot summer day, the density of air at atmospheric pressure at 35.0C is 1.1455 kg/m3. a. What is the number of moles contained in 1.00 m3 of an ideal gas at this temperature and pressure? b. Avogadros number of air molecules has a mass of 2.85 102 kg. What is the mass of 1.00 m3 of air? c. Does the value calculated in part (b) agree with the stated density of air at this temperature?
- An ideal gas is trapped inside a tube of uniform cross-sectional area sealed at one end as shown in Figure P19.49. A column of mercury separates the gas from the outside. The tube can be turned in a vertical plane. In Figure P19.49A, the column of air in the tube has length L1, whereas in Figure P19.49B, the column of air has length L2. Find an expression (in terms of the parameters given) for the length L3 of the column of air in Figure P19.49C, when the tube is inclined at an angle with respect to the vertical. FIGURE P19.49(a) Given that air is 21% oxygen, find the minimum atmospheric pressure that gives a relatively safe partial pressure of oxygen of 0.16 atm. (b) What is the minimum pressure that gives a partial pressure of oxygen above the quickly fatal level of 0.06 atm? (c) The air pressure at the summit of Mount Everest (8848 m) is 0.334 atm. Why have a few people climbed it without oxygen, while some who have tried, even though they had trained at high elevation, had to tum back?Cylinder A contains oxygen (O2) gas, and cylinder B contains nitrogen (N2) gas. If the molecules in the two cylinders have the same rms speeds, which of the following statements is false? (a) The two gases haw different temperatures. (b) The temperature of cylinder B is less than the temperature of cylinder A. (c) The temperature of cylinder B is greater than the temperature of cylinder A. (d) The average kinetic energy of the nitrogen molecules is less than the average kinetic energy of the oxygen molecules.
- A vertical cylinder of cross-sectional area A is fitted with a tight-fitting, frictionless piston of mass m (Fig. P18.40). The piston is not restricted in its motion in any way and is supported by the gas at pressure P below it. Atmospheric pressure is P0. We wish to find the height h in Figure P18.40. (a) What analysis model is appropriate to describe the piston? (b) Write an appropriate force equation for the piston from this analysis model in terms of P, P0, m, A, and g. (c) Suppose n moles of an ideal gas are in the cylinder at a temperature of T. Substitute for P in your answer to part (b) to find the height h of the piston above the bottom of the cylinder. Figure P18.40A gas is in a container of volume V0 at pressure P0. It is being pumped out of the container by a piston pump. Each stroke of the piston removes a volume Vs through valve A and then pushes the air out through valve B as shown in Figure P19.74. Derive an expression that relates the pressure Pn of the remaining gas to the number of strokes n that have been applied to the container. FIGURE P19.74A deepsea diver should breathe a gas mixture that has the same oxygen partial pressure as at sea level, where dry air contains 20.9% oxygen and has a total pressure of 1.01105N/m2. (a) What is me partial pressure of oxygen at sea level? (b) If the diver breathes a gas mixture at a pressure of 2.00106N/m2, what percent oxygen should it be to have the same oxygen partial pressure as at sea level?