Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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A 1.00 L rigid cylinder contains one mole of neon gas at 25 °C. Calculate the pressure using (a) the ideal gas law, and (b) the van der Waals equation. (c) A much more accurate equation is the virial equation, RT Vm= 1+ B(T) C(T) where B(T) and C(T) are functions of temperature. For neon at 25°C, the values of B(T) and C(T) are 11.42 cm mol and 221 cm mol-2, respectively. Assuming the pressure calculated using the virial equation is the "true" value, determine the percent error by using ideal gas law and van der Waals equation.

A 1.00 L rigid cylinder contains one mole of neon gas at 25 °C. Calculate the pressure
using (a) the ideal gas law, and (b) the van der Waals equation.
(c) A much more accurate equation is the virial equation,
B(T)
1+
+
Vm
p/m
C(T)
RT
where B(T) and C(T) are functions of temperature. For neon at 25°C, the values of B(T)
and C(T) are 11.42 cm3 mol-1 and 221 cm mol-2, respectively. Assuming the pressure
calculated using the virial equation is the "true" value, determine the percent error by
using ideal gas law and van der Waals equation.
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Transcribed Image Text:A 1.00 L rigid cylinder contains one mole of neon gas at 25 °C. Calculate the pressure using (a) the ideal gas law, and (b) the van der Waals equation. (c) A much more accurate equation is the virial equation, B(T) 1+ + Vm p/m C(T) RT where B(T) and C(T) are functions of temperature. For neon at 25°C, the values of B(T) and C(T) are 11.42 cm3 mol-1 and 221 cm mol-2, respectively. Assuming the pressure calculated using the virial equation is the "true" value, determine the percent error by using ideal gas law and van der Waals equation.
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