Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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- Pure liquid ammonia ionizes in a manner similar to that of water. (a) Write the equilibrium for the autoionization of liquid ammonia. (b) Identify the conjugate acid form and the base form of the solvent. (c) Is NaNH2 an acid or a base in this solvent? (d) Is ammonium bromide an acid or a base in this solvent?arrow_forwardTo measure the relative strengths of bases stronger than OH, it is necessary to choose a solvent that is a weaker acid than water. One such solvent is liquid ammonia. (a) Write a chemical equation for the autoionization of ammonia. (b) What is the strongest acid and base that can exist in liquid ammonia? (c) Will a solution of HCI in liquid ammonia be a strong electrical conductor, a weak conductor, or a nonconductor? (d) Oxide ion (O2) is a stronger base than the amide ion (NH2). Write an equation for the reaction of O2 with NH3 in liquid ammonia. Will the equilibrium favor products or reactants?arrow_forwardUsing the diagrams shown in Problem 10-37, which of the four acids is the weakest acid?arrow_forward
- Ethanol (ethyl alcohol), CH3CH2OH, can act as a BrnstedLowry acid. Write the chemical equation for the reaction of ethanol as an acid with hydroxide ion, OH. Ethanol can also react as a BrnstedLowry base. Write the chemical equation for the reaction of ethanol as a base with hydronium ion, H3O+. Explain how you arrived at these chemical equations. Both of these reactions can also be considered Lewis acid base reactions. Explain this.arrow_forwardWhich acid has the strongest conjugate base? (a) HNO2 (b) C6H5CO2H (c) HCN (d) HClarrow_forwardIn each of the following acid-base reactions, identify the Brnsted acid and base on the left and their conjugate partners on the right. (a) HCO2H(aq) + H2O() HCO2(aq) + H3O+(aq) (b) NH3(aq) + H2S(aq) NH4+(aq) + HS(aq) (c) HSO4(aq) + OH(aq) SO42(aq) + H2O+()arrow_forward
- Which of the following substances are acids in terms of the Arrhenius concept? Which are bases? Show the acid or base character by using chemical equations. a P4O10 b Na2O c N2H4 d H2Tearrow_forwardFor oxyacids, how does acid strength depend on a. the strength of the bond to the acidic hydrogen atom? b. the electronegativity of the element bonded to the oxygen atom that bears the acidic hydrogen? c. the number of oxygen atoms? How does the strength of a conjugate base depend on these factors? What type of solution forms when a nonmetal oxide dissolves in water? Give an example of such an oxide. What type of solution forms when a metal oxide dissolves in water? Give an example of such an oxide.arrow_forwardWhich of the terms weak, strong, monoprotic, diprotic, and triprotic characterize(s) each of the following acids? More than one term may apply in a given situation. a. HC3H3O3 b. HCN c. H2SO4 d. H2SO3arrow_forward
- Consider the following four solutions: (1) apple juice, pH 3.8, (2) pickle juice, pH 3.5, (3) carbonated beverage, pH 3.0, and (4) drinking water, pH 7.2. a. Which solution has the highest [H3O+]? b. Which solution has the highest [OH]? c. List the solutions in order of increasing acidity. d. List the solutions in order of decreasing basicity.arrow_forwardWhich of the terms weak, strong, monoprotic, diprotic, and triprotic characterize(s) each of the following acids? More than one term may apply in a given situation. a. H3PO4 b. H3PO3 c. HBr d. HC2H3O2arrow_forwardIn each of the following acid-base reactions, identify the Brnsted acid and base on the left and their conjugate partners on the right. (a) C2H5N(aq) + CH3CO2H(aq) C5H5NH+(aq) + CH3CO2(aq) (b) N2H4(aq) + HSO4(aq) N2H5+(aq) + SO42(aq) (c) [Al(H2O)6]3+ (aq) + OH(aq) [Al(H2O)5OH]2+ (aq) + H2O+()arrow_forward
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