6. Carbonyl chloride fluoride (COFCI) belongs to the Cs point group, which has the relatively simple character table shown below. Cs EOh A' 1 1 x, y, R₂ A" 1 -1 Z, Rx, Ry 6.1 How many translational degrees of freedom does COFCI have? x², y², z², xy yz, zx 6.2 How many rotational degrees of freedom does COFCI have? 63 How many vibrational degrees of freedom does COFCI have? 6.4 The displacement vectors for the atoms of COFCI span 8 A' + 4 A". What are the symmetry species of the normal modes of vibration? 6.5 How many of the vibrational modes of COFCI are IR active? J 6.6 How many of the vibrational modes of COFCI are Raman active?
6. Carbonyl chloride fluoride (COFCI) belongs to the Cs point group, which has the relatively simple character table shown below. Cs EOh A' 1 1 x, y, R₂ A" 1 -1 Z, Rx, Ry 6.1 How many translational degrees of freedom does COFCI have? x², y², z², xy yz, zx 6.2 How many rotational degrees of freedom does COFCI have? 63 How many vibrational degrees of freedom does COFCI have? 6.4 The displacement vectors for the atoms of COFCI span 8 A' + 4 A". What are the symmetry species of the normal modes of vibration? 6.5 How many of the vibrational modes of COFCI are IR active? J 6.6 How many of the vibrational modes of COFCI are Raman active?
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter13: Introduction To Symmetry In Quantum Mechanics
Section: Chapter Questions
Problem 13.21E
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