Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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- You are carrying out a reaction in the laboratory. You need to convert 1.00 mole of reactant X into products. This reaction shows first-order kinetics, and the reaction mixture has a constant volume of 1.00 L. At 1:00pm, you start the reaction at 25\deg C with 1.00 mole of reactant X. At 2:00pm, you find that 0.70 moles of reactant X remain. You immediately increase the temperature of the reaction mixture to 35\deg C. At 3:00pm, you discover that 0.25 moles of reactant X are still present. You want to be able to finish the reaction by 4:00pm, but you cannot stop the reaction until only 0.01 moles of reactant X remain. You must increase the temperature again. What is the minimum temperature required to complete the reaction by 4:00pm? (Remember, the reaction is complete when only 0.01 moles of X remain.)arrow_forwardConsider the following potential energy diagram: * 1 p Reaction A Reaction B potential potential energy energy Reaction Pathway Reaction Pathway Reaction A is exothermic while Reaction B is endothermic Reaction A is endothermic while Reaction B is exothermic Reaction A will most likely be spontaneous while Reaction B is unlikely to be spontaneous O Reaction A releases heat while Reaction B absorbs heatarrow_forwardThe rate constant k for a certain reaction is measured at two different temperatures: temperature k 325.0 °C |1.7 × 1012 456.0 °C |3.0 × 1013 Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy E, for this reaction. Round your answer to 2 significant digits. kJ E = Ox10 molarrow_forward
- -2 The hydrolysis of urea by urease occurs in a batch bioreactor. The reaction follows a Michaelis- Menten mechanism. The following kinetic data are available for urea: K'm=7.7×10 M, v =0.5 mole/L/min. The initial concentration of urea in the reactor is 50 mole/L. m E+S ES-²E + P Vm[S] Km + [S] Calculate the concentration of urea in the reactor 10 minutes after the reaction starts v= (Hint: it is a batch reactor, meaning that you need to integrate the MM, see module 1 for details of batch reactors).arrow_forwardIn a batch reactor, a substance A was processed, which generated different products (D and U), through competitive parallel reactions with the following reaction kinetics: After 20 minutes of reaction, it was determined that the composition of the reaction medium was CA = 1 mol/L, CD = 5 mol/L, CU = 2 mol/L. The option that indicates, respectively, the instantaneous and global selectivities at the end of the reaction are: A) 3 and 2. B) 2.5 and 2. C) 2 and 3. D) 2 and 2.5.arrow_forwardThe elementary gas-phase reaction A → 3B is carried out in a cylindrical batch reactor divided by a thin metallic membrane into two compartments of equal volume, as shown in the figure below. Pure A Pure I Initially one side is filled with pure 'A', and the other with an inert gas T. Both sides are at the same pressure (1 atm.), the same temperature, and contain the same number of moles. The reaction is carried out isothermally and the rate constant for the reaction is 0.1 min. a. After 10 minutes the membrane ruptures. What is the pressure differential rating of the membrane? What is the conversion at this time? b. If the mixture continues to react after the membrane is ruptured, how much longer does it take for the conversion to reach 90% (based on the initial moles of A)? c. Sketch the pressure versus time behavior for the entire duration. Mark all the important values on your diagram. HINT; Note that in each phase (before and after rupture) the reaction is occurring in a constant…arrow_forward
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