Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- A 100.0 mL sample of 0.250 M NaOH is mixed with a 150.0 mL sample of 0.280 M HNO3 in a coffee cup calorimeter. Both solutions were initially at 35.00°C and after mixing, the temperature of the resulting solution was recorded as 37.00°C. Determine the enthalpy of neutralization (ΔH°neutralization rxn) (in units of kJ/mol) for the neutralization reaction between aqueous NaOH and HNO3. The specific heat capacity of water = 4.184 J/g°C and density of water = 1.00 g/mL Assume 1) that no heat is lost to the calorimeter or the surroundings, and 2) that the density and the heat capacity of the resulting solution are the same as water. Hint: Heat of neutralization is the enthalpy change per mol of water formed in a neutralization reaction. Write the balanced equation, calculate the limiting reactant and the mol of water formed in the reaction. Enter the numerical value clearly indicating whether it is endothermic or exothermic.arrow_forwardA student performed this experiment by mixing 50.0 mL of 2.0 M NaOH solution with 50.0 mL of 2.0 M HCl solution. The student found the temperature change for this reaction to be 12.4º C. Assuming the density of the solution was 1.03 g/mL, the Cp for the solution is the specific heat for water (4.184 J/g℃) and the Ccal is 18.1 J/℃. Determine the amount of heat absorbed by the calorimeter (qcal).arrow_forwardDerive enthalpies of physical and chemical processes from coffee cup calorimeter data. Potassium hydroxide pellets (KOH) are placed in 100.00 mL of water. The mass of KOH used is 40.005 g. The enthalpy of solution for potassium hydroxide is shown in a reaction below. It releases 57.6 kJ/mol. Use 0.99802 g/mL for the density of water. What will be the final temperature if the initial water temperature is 21 °C? КОН() -> КОН(aq) AH = – 57.6 kJ/molarrow_forward
- In a coffee cup calorimeter, a student places 0.500 g of calcium, followed by addition of 50.0 mL of 1.00 M hydrochloric acid. After the reaction took place, a temperature change of 24.7oC was observed. If the reaction solution has the same properties of water and the calorimeter constant is 5.10 J oC-1, what is the enthalpy of reaction in kJ mol-1? (Note: The mass of solution is the mass of all components added.)arrow_forward22.68g of an unknown sample, with a molar mass of 53.90g/mol, reacts with excess reagents inside a simple calorimeter. The outside of the calorimeter is made of an aluminum cup with a mass of 81.0g. There is 136g of water inside the calorimeter. The temperature of the entire calorimeter increases from 20.0°C to 22.9°C. What is the molar enthalpy of reaction, in kJ/mol, with respect to the unknown?arrow_forwardWhen 35.0 mL of 0.250 M acetic acid solution, initially at 25.00oC, is added to excess dilute sodium hydroxide solution, also initially at 25.00oC, in a neutralization reaction, in a calorimeter, the temperature increases to 26.35 oC. The mass of the final solution is 85.0 g. Assuming the specific heat of the solution and products is 4.18 J/goC. Calculate the enthalpy change in kJ, Δ H, for this reaction.HC2H3O2(aq) + NaOH(aq) --> NaC2H3O3(aq) + H2O(l)arrow_forward
- 6. 100.0 mL of 1.00 M of HCl and 100.0 mL of 2.00 M of Ca(OH)2 are mixed at 298K. During the experiment, the temperature rose to 298.0067 K. Assume the heat capacities of the two solutions and densities are the same as that of water (4.184 J/g °C and 1.00 g/mL). Calculate the heat of neutralization in units of (kJ/mol H₂0 produced).arrow_forwardTwo student chemists measured 25.0mL of 1.00 M NaOH in separate calorimeters as in the experimental procedure, Part B. Student 1 added 25.0mL of 1.10 M HCl in his solution of NaOH. Student 2 added 22.7mL of 1.10 M HCl in his NaOH solution. Each student recorded the temperature change and calculated the enthalpy of neutralization. Complete the following table to assist in answering the below questions. NOTE: Limiting reactant needs to be identified to calculate the enthalpy of neutralization. Student 1 Moles of NaOH _________ Moles of HCl added _________ Limiting reactant _________ Moles of H2O produced _________ Mass of final mixture _________ Student 2 Moles of NaOH _________ Moles of HCl added _________ Limiting reactant _________ Moles of H2O produced _________ Mass of final mixture _________ Explain why and how (higher or lower) the temperature will be different for the two…arrow_forwardIn a calorimetry experiment similar to the one performed today, a student used 50.0 ml of 1.0 m NaOH and 5.0 ml of 1.0 m HCL each initially at 22.5ºC. The max temp observed after mixing was 28.0º C. What is the heat of reaction in units of kJ ?arrow_forward
- 4. Suppose 5 mL of 1.5 M ethylene diamine is added to 50 mL of 0.15 M Ni? solution in an identical calorimeter used in this experiment. The temperature rose 1.10°. Using the value for c of solution and C of the calorimeter, calculate AH for the formation of the ethylenediamine bonds. in kJ/mol.arrow_forward7. The heat evolved from the combustion of 0.94g ethanol raises the temperature of 250 cm³ water contained in a copper beaker by 20.0 °C. [Specific heat capacity of solution = 4.18 Jg1 °C; density of solution = 1.0 g cm-3] i) What is the enthalpy of combustion per mol of ethanol? ii) Calculate the temperature rise when 1.50 g ethanol is used to heat 500 cm3 water in the same copper beaker.arrow_forwardIn a constant-pressure calorimeter, 50.0mL of 0.340MBa(OH)2 was added to 50.0mL of 0.680MHCI. The reaction caused the temperature of the solution to rise from 23.86°C to 28.49°C. If the solution has the same density and specific heat as water, what is heat absorbed by the solution? Assume that the total volume is the sum of the individual volumes. (And notice that the answer is in kJ). Q =arrow_forward
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