Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Related questions
Question
thumb_up100%
Transcribed Image Text:4.
You prepare several dilutions of an unknown compound. You measure the
absorbance of each solution at 340 nm using a 1 cm cuvette (your results are listed in the table
below). What is the extinction coefficient (in (M•cm)') of the compound? (Hint: assume that
each of the individual values contains some degree of experimental error.)
Concentration(uM)
Absorbance at 340 nm
10.0
0.011
20.0
0.023
40.0
0.066
80.0
0.119
160.0
0.189
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution
Trending nowThis is a popular solution!
Step by stepSolved in 2 steps with 4 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Absorbance Beer-Lambert's Law (Spectrophotometry) #2 To spectrophotometrically determine the mass percent of cobalt in an ore containing cobalt and some inert materials, solutions with known [Co"] are prepared and the absorbance of each of the solutions is measured at the wavelength of optimum absorbance. The data are used to create a calibration plot, shown below. 0.80 0.70- 8 0.60- 0.50- 0.40- 0.30 0.20- 0.10- ++- 0.015 Concentration (M) A 0.6 g sample of the ore is completely dissolved in concentrated HNO3(aq). The mixture is diluted with 2+ water to a final volume of 50.00 mL. Assume that all the cobalt in the ore sample is converted to Co'(aq). a. What is the (Co] in the solution if the absorbance of a sample of the solution is 0.74? b. Calculate the number of moles of CoT(ag) in the 50.00 mL solution. 2+ C. Calculate the mass percent of Co in the 0.630 g sample of the ore.arrow_forwardWhat is the concentration of FeSCN2+ in each standard solution? (Show ALL calculations for each solution) Stock Solution of the concentration of FeSCN^2+ is 0.00200 Marrow_forwardYou were tasked to separate the components of a mixture containing silica, sodium chloride and charcoal. TNāCI dissolves in water while silica and charcoal are not water-soluble. Only charcoal dissolves in carbon disulfide. a. Write a short experimental procedure to carry out the separation of the mixture. b. Given the following data, determine the percentage of charcoal, sodium chloride and silica. Mass (g) Mass of beaker 100.000 Mass of beaker + mixture 110.000 mass of evaporating dish 62.000 mass of evaporating dish + solid after evaporation of water 65.000 Mass of beaker + charcoal + silica after evaporation of excess water 117.000 mass of beaker + silica after decanting dissolved charcoal and drying 113.545arrow_forward
- For Question 2 and 3 please refer to the following diagram. The following data and diagram represent the relationship between absorbance and concentration of nitrate. Concentration Absorbance of nitrate (M) 0.0487 0.0731 1.2 0.346 0.521 0.652 0.8 0.6 0.0974 0.4 0.122 0.868 0.2 0.146 1.042 0.05 0.1 0.15 0.2 The above graph is incorrect. Use graph paper or excel tools, plot a suitable graph to represent the relation between absorbance and concentration of nitrate with the equation 2. 1.arrow_forward1. A company illegally dumped their wastewater on a river bank. You are part of an environmental NGO that are tasked to determine what kind toxins that may have contaminated the waters. What kind of analysis would you do? a. Characterization analysis b. Qualitative analysis c. Fundamental analysis d. Quantitative analysis 2. Four groups weighed ten rock samples each, and tested the possibility of outliers using Q-test. At 95.0% confidence (a = 0.05), which of the following is considered to be an outlier? a. 0.024 b. 0.413 c. 0.453 d. 0.674 3. An unknown solution containing oxalic acid, which is a diprotic acid, is titrated against sodium hydroxide. How many mole/s of titrant is needed to react with one mole of analyte? a. ½ b. ¼ c. 2 d. 4arrow_forwardA. Copper sulfate pentahydrate is often used to teach students about Beer’s Law by making a standard curve (linear regression). The bright blue color of the solution has a peak absorbance in the red range of the electromagnetic spectrum. The absorbance value is proportional to concentration. How many grams of CuSO4 5H2O to make up 250 mL of a 0.2 M stock of this solution? B. Using M1V1 = M2V2 how many mL would a student need to measure out in graduated cylinder to make up a 50 mL (V2) solution of 0.1M, 0.05 M, 0.025M 0.0125M solutions for a standard curve at the peak wavelenth for this compound?arrow_forward
- The absorbance of a cationic iron(II) sample solution was measured in a spectrophotometer, but the instrument returned an error because the absorbance was too high. The sample was then diluted by using a pipette to take 100.0 μLμL of the sample and injecting it into a cuvette already containing 2.00 mLmL of water (total volume is 2.00 mLmL + 100.0 μLμL). The absorbance value of the diluted solution corresponded to a concentration of 7.71×10−6 M M . What was the concentration of the original solution? Express the concentration to three significant figures with the appropriate units.arrow_forwardPlease helparrow_forwardBen ran through the experiment and found the best-fit line listed below for his standard calibration curve of absorbance vs concentration in M. y = 3214.0x + 0.0076 Ben then prepared a solution that had 5.00 mL 0.002 M iron(III) nitrate in 1 M nitric acid, 3.00 mL 0.002 M potassium thiocyanate, and 2.00 mL DI water. If the absorbance for the solution was 0.436, calculate the equilibrium concentration of iron(III) thiocyanate in the solution. Report your answer in mM with three places after the decimal.arrow_forward
- y= 0.0624x+0.0123 R^2=0.9867arrow_forwardYou are preparing a 100.0 mL standard solution needed for titration analysis. The NaOH (40 g/mol) pellets are measured to be 0.5341 g in a balance with acceptable uncertainty of +0.001 g. Mass of the pellets is recorded after taring the container. The pellets are put in a beaker and added with 50 ml distilled water measured by a graduated cylinder. The solution is then quantitatively transferred to a 100-mL volumetric flask with uncertainty of ±0.08 mL and diluted to a 100-mL mark. What is the concentration (M) of the solution and estimate its uncertainty by propagation? Assumption: There is no uncertainty in molar mass. Express your answer as C+/- u M.arrow_forwardWhat is the H2S content of the solution (in mg/dm3 unit) of which 20 cm3 reacts with 40 mgof Br2.MM[H2S]=34.08 g/mol; MM[Br2]=159.8 g/molarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning 
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY