4. Provide the product for the following reaction. Provide the sterochemistry and regiochemistry where is appropriate. Show the mechanism for each reaction 1) ВНа-THF 2) но , NaOH а) 1) BH3•THF b) 2) HаОг. NaOH 1) BH3•THF 2) H-0г. NaOH c) 1) BH3•THF d) 2) HОг. NaOH 1) ВНа-THF 2) HОг. NaOH 1) BH3•THF 2) HОг. NaOH f)

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter19: Eas: Electrophilic Aromatic Substitution
Section: Chapter Questions
Problem 18CTQ
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parts a, b, c, d, e, and f

4. Provide the product for the following reaction. Provide the sterochemistry and
regiochemistry where is appropriate. Show the mechanism for each reaction
1) BH3 THF
2) но , NaOH
a)
1) ВНз-THF
b)
2) Hа0г. NaOH
1) BH3•THF
2) H2O2, NaOH
1) BH3•THF
d)
2) H2Ог. NaOH
1) ВНз-THF
2) Hа0г. NaOH
1) BH3• THF
f)
2) H2Ог. NaOH
Transcribed Image Text:4. Provide the product for the following reaction. Provide the sterochemistry and regiochemistry where is appropriate. Show the mechanism for each reaction 1) BH3 THF 2) но , NaOH a) 1) ВНз-THF b) 2) Hа0г. NaOH 1) BH3•THF 2) H2O2, NaOH 1) BH3•THF d) 2) H2Ог. NaOH 1) ВНз-THF 2) Hа0г. NaOH 1) BH3• THF f) 2) H2Ог. NaOH
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Given reaction:

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Step 3

The addition of boron hydride in the presence of tetrahydrofuran and in presence of peroxide in alkaline medium to form alcohol is a hydroboration oxidation reaction. Hydroboration oxidation follows antimarkovnikov rule.

Antimarkovnikov rule states that during addition reaction in alkene, the negative part of the adding molecule will get attached to that carbon which contains more number of hydrogen atoms.

Step 4

Thus, the mechanism for given reactions is represented as follows:

Chemistry homework question answer, step 4, image 1

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