
Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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38.7 g of non-disassociating compound is dissolved into 218.0 g of water. The freezing point of the solution is measured to be -5.53 °C. Calculate the molar mass of the solute in the solution
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- A patient has a “cholesterol count” of 214. Like manyblood-chemistry measurements,this result is measured inunits of milligrams per deciliter (mgdL1). Determine the molar concentration of cholesterol inthis patient’s blood, taking the molar mass of cholesterolto be 386.64gmol1. Estimate the molality of cholesterol in the patient’sblood. If 214 is a typical cholesterol reading among men inthe United States, determine the volume of such bloodrequired to furnish 8.10 g of cholesterol.arrow_forwardDistinguish between dispersion methods and condensation methods for preparing colloidal systems.arrow_forwardVapor-pressure lowering is a colligative property, as are freezing-point depression and boiling-point elevation. What is a colligative property? Why is the freezing point depressed for a solution as compared to the pure solvent? Why is the boiling point elevated for a solution as compared to the pure solvent? Explain how to calculate T for a freezing-point depression problem or a boiling-point elevation problem. Of the solvents listed in Table 10-5, which would have the largest freezing-point depression for a 0.50 molal solution? Which would have the smallest boiling-point elevation for a 0.50 molal solution? A common application of freezing-point depression and boiling-point elevation experiments is to provide a means to calculate the molar mass of a nonvolatile solute. What data are needed to calculate the molar mass of a nonvolatile solute? Explain how you would manipulate these data to calculate the molar mass of the nonvolatile solute.arrow_forward
- The vapor pressure of an aqueous solution of urea. CH4N2O, is 291.2 mmHg at a measured temperature. The vapor pressure of pure water at that temperature is 355.1 mmHg. Calculate the mole fraction of each component.arrow_forwardFreezing point depression is one means of determining the molar mass of a compound. The freezing point depression constant of benzene is 5.12 C/m. a. When a 0.503 g sample of the white crystalline dimer is dissolved in 10.0 g benzene, the freezing point of benzene is decreased by 0542 C. Verify that the molar mass of the dimer is 475 g/mol when determined by freezing point depression. Assume no dissociation of the dimer occurs. b. The correct molar mass of the dimer is 487 g/mol. Explain why the dissociation equilibrium causes the freezing point depression calculation to yield a lower molar mass for the dimer.arrow_forwardA 2.77 M NaOH solution in water has a density of 1.109 g/mL. Express the concentration of this solution (a) mass percentage. (b) mole fraction. (c) molality.arrow_forward
- An unknown compound contains only carbon, hydrogen, and oxygen. Combustion analysis of the compound gives mass percents of 31.57% C and 5.30% H. The molar mass is determined by measuring the freezing-point depression of an aqueous solution. A freezing point of 5.20C is recorded for a solution made by dissolving 10.56 g of the compound in 25.0 g water. Determine the empirical formula, molar mass, and molecular formula of the compound. Assume that the compound is a nonelectrolyte.arrow_forwardA forensic chemist is given a white solid that is suspected of being pure cocaine (C17H21NO4, molar mass = 303.35 g/mol). She dissolves 1.22 0.01 g of the solid in 15.60 0.01 g benzene. The freezing point is lowered by 1.32 0.04C. a. What is the molar mass of the substance? Assuming that the percent uncertainty in the calculated molar mass is the same as the percent uncertainty in the temperature change, calculate the uncertainty in the molar mass. b. Could the chemist unequivocally state that the substance is cocaine? For example, is the uncertainty small enough to distinguish cocaine from codeine (C18H21NO3, molar mass = 299.36 g/mol)? c. Assuming that the absolute uncertainties in the measurements of temperature and mass remain unchanged, how could the chemist improve the precision of her results?arrow_forward
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