38. (a) How many grams of NaOAc must be added to 300 ml 0.01 M HOAC to produce a buffer of pH 6.50? (b) 2.00 mM NAOH is added to the buffer above. What is the pH after the addition of the base? (c) What would happen to the buffer if 2.00 mM NAOH additional were introduced? Ans. (a) 14 g.; (b) 7; (c) pH becomes 11.53.

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38. (a) How many grams of NaOAc must be added to 300 ml 0.01 M
HOAC to produce a buffer of pH 6.50?
(b) 2.00 mM NAOH is added to the buffer above. What is the pH after
the addition of the base?
(c) What would happen to the buffer if 2.00 mM NAOH additional were
introduced?
Ans. (a) 14 g.; (b) 7; (c) pH becomes 11.53.
Transcribed Image Text:38. (a) How many grams of NaOAc must be added to 300 ml 0.01 M HOAC to produce a buffer of pH 6.50? (b) 2.00 mM NAOH is added to the buffer above. What is the pH after the addition of the base? (c) What would happen to the buffer if 2.00 mM NAOH additional were introduced? Ans. (a) 14 g.; (b) 7; (c) pH becomes 11.53.
30. The base (CH2)3N has an ionization constant of 7 x 10-5. If 50 ml
0.1 N (CH3)3N is titrated with 0.1 N HCl:
(a) Find the pH before any acid is added.
(b) Find the pH at the equivalence point.
(c) Find the pH when the base is two-fifths neutralized.
(d) Draw the approximate titration curve.
(e) What indicator should be used?
31. Repeat the calculations of problem 29 for the neutralization of 50 ml
0.001 N HA by 0.001 N NaOH, assuming an initial volume of 200 ml.
Transcribed Image Text:30. The base (CH2)3N has an ionization constant of 7 x 10-5. If 50 ml 0.1 N (CH3)3N is titrated with 0.1 N HCl: (a) Find the pH before any acid is added. (b) Find the pH at the equivalence point. (c) Find the pH when the base is two-fifths neutralized. (d) Draw the approximate titration curve. (e) What indicator should be used? 31. Repeat the calculations of problem 29 for the neutralization of 50 ml 0.001 N HA by 0.001 N NaOH, assuming an initial volume of 200 ml.
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