3.27 Suggest structures for alkenes that give the following reaction products. There may be more than one answer for some cases. (a) CH3 CH3CHCH₂CH₂CH₂CH3 (c) (e) ? ? ? H₂/Pd Br2. Br CH3 CH3CHCHCH₂CHCH3 Br 1. Hg(OAc)2, H₂O 2. NaBH4 OH CH3CH₂CH₂CHCH3 (b) (d) (f) ? ? ? H₂/Pd HCI CI CH₂12, Zn/Cu CH3 CH3 CH3CHCHCH₂CH₂CH₂CH3 CH3 X edict th he m

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3.27 Suggest structures for alkenes that give the following reaction products. There
may be more than one answer for some cases.
(a)
CH3
CH3CHCH₂CH₂CH₂CH3
(c)
(e)
?
(c)
?
?
H₂/Pd
Br2.
Br
1. Hg(OAc)2, H₂O
2. NaBH4
H
CH3CHCHCH₂CHCH3
Br
CH3
CH3
CH3CH₂CH₂CHCH3
1.03
2. Zn, H3O+
1. BH3
2. H₂0₂, OH
OH
?
?
(b)
(d)
(b)
(d)
cis-CH3CH=CHCH3
trans-CH₂CH=CHCH3
(f)
?
.28 Predict the products of the following reactions, showing both regiochemistry
and stereochemistry where appropriate:
(a)
CH3
?
?
H₂/Pd
HCI
CH3
CH₂12, Zn/Cu
KMnO4
H3O+
?
CI
CH₂12, Zn(Cu)
1. Hg(OAc)2, H₂O
2. NaBH4
CH3CHCHCH₂CH₂CH₂CH3
CH3
CH₂I2, Zn(Cu)
CH3
.31 The cis and trans isomers of 2-butene give different cyclopropane products in
the Simmons-Smith reaction. Show the structures of both, and explain the
difference.
CH3
?
?
?
edict th
he m
Transcribed Image Text:3.27 Suggest structures for alkenes that give the following reaction products. There may be more than one answer for some cases. (a) CH3 CH3CHCH₂CH₂CH₂CH3 (c) (e) ? (c) ? ? H₂/Pd Br2. Br 1. Hg(OAc)2, H₂O 2. NaBH4 H CH3CHCHCH₂CHCH3 Br CH3 CH3 CH3CH₂CH₂CHCH3 1.03 2. Zn, H3O+ 1. BH3 2. H₂0₂, OH OH ? ? (b) (d) (b) (d) cis-CH3CH=CHCH3 trans-CH₂CH=CHCH3 (f) ? .28 Predict the products of the following reactions, showing both regiochemistry and stereochemistry where appropriate: (a) CH3 ? ? H₂/Pd HCI CH3 CH₂12, Zn/Cu KMnO4 H3O+ ? CI CH₂12, Zn(Cu) 1. Hg(OAc)2, H₂O 2. NaBH4 CH3CHCHCH₂CH₂CH₂CH3 CH3 CH₂I2, Zn(Cu) CH3 .31 The cis and trans isomers of 2-butene give different cyclopropane products in the Simmons-Smith reaction. Show the structures of both, and explain the difference. CH3 ? ? ? edict th he m
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