Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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3. Two cyclic products are possible from the Dieckmann condensation shown below, but only
one product forms.
1. NaOEt, EtOH
EtO
OEt
2. H3O+
a. Provide the product of the Dieckmann condensation shown above.
b. Provide a complete mechanism, using appropriate curved arrows to show the direction of
electron flow, for the Dieckmann condensation. You must show the correct formal charges on
atoms at each step. You must write out the full structure of each intermediate using an
accepted chemical style. Clearly indicate which steps are reversible or unidirectional with the
correct reaction arrows.
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Transcribed Image Text:3. Two cyclic products are possible from the Dieckmann condensation shown below, but only one product forms. 1. NaOEt, EtOH EtO OEt 2. H3O+ a. Provide the product of the Dieckmann condensation shown above. b. Provide a complete mechanism, using appropriate curved arrows to show the direction of electron flow, for the Dieckmann condensation. You must show the correct formal charges on atoms at each step. You must write out the full structure of each intermediate using an accepted chemical style. Clearly indicate which steps are reversible or unidirectional with the correct reaction arrows.
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