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3. Identify C-Cl stretching peaks in CDCI3 and CHCI3 spectra. Do these peaks have exactly the same frequencies for both compounds? Explain your answer.

3. Identify C-Cl stretching peaks in CDCI3 and CHCI3 spectra. Do these peaks have exactly the same frequencies for both compounds? Explain your answer.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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3. Identify C-Cl stretching peaks in CDC13 and CHC13 spectra. Do these peaks have exactly the same frequencies for both compounds? Explain your answer. 4. Is the C==O stretching frequency the same for acetone and deuterated acetone? Explain your answer. 5. Identify C==O overtone in acetone spectrum which corresponds to the transition from ground level, n=0, to the second excited level, n=2.
Transcribed Image Text:3. Identify C-Cl stretching peaks in CDC13 and CHC13 spectra. Do these peaks have exactly the same frequencies for both compounds? Explain your answer. 4. Is the C==O stretching frequency the same for acetone and deuterated acetone? Explain your answer. 5. Identify C==O overtone in acetone spectrum which corresponds to the transition from ground level, n=0, to the second excited level, n=2.
Clipboard Font Alignment Number Styles Cells Editing Analysis Sensitivity Chart 5 fx В C E F G H K M Q R S Format Plot Area 1 v(cm-1) 3.99E+02 1.04E+02 1.03E+02 4.01E+02 1.08E+02 1.07E+02 4.03E+02 1.08E+02 1.07E+02 4.05E+02 1.06E+02 1.05E+02 4.07E+02 1.05E+02 1.06E+02 4.09E+02 1.06E+02 1.05E+02 4.11E+02 1.06E+02 1.05E+02 4.13E+02 1.06E+02 1.06E+02 |Chlorform Chlorform|D 110 O 2 Plot Area Options v 3 4 100 5 6 1 Border 90 7 O No line 8 9 O Solid line 80 10 4.15E+02 1.06E+02 1.06E+02 11 4.17E+02 1.07E+02 1.06E+02 12 4.18E+02 1.07E+02 1.06E+02 13 4.20E+02 1.06E+02 1.06E+02 14 4.22E+02 1.06E+02 1.06E+02 15 4.24E+02 1.06E+02 1.06E+02 16 4.26E+02 1.07E+02 1.06E+02 17 4.28E+02 1.08E+02 1.06E+02 18 4.30E+02 1.07E+02 1.06E+02 19 4.32E+02 1.07E+02 1.06E+02 20 4.34E+02 1.08E+02 1.06E+02 21 4.36E+02 1.08E+02 1.07E+02 22 4.38E+02 1.08E+02 1.06E+02 23 4.40E+02 1.07E+02 1.07E+02 24 4.42E+02 1.07E+02 1.07E+02 25 4.44E+02 1.08E+02 1.07E+02 26 4.45E+02 1.07E+02 1.07E+02 27 4.47E+02 1.08E+02 1.07E+02 28 4.49E+02 1.08E+02 1.08E+02 O Gradient line O Automatic 70 - Chlorform Chlorform D Color 60 Iransparency H 0% Width 1.75 pt 50 Compound type Dash type 40 Сap type Flat Join type Rounc 30 Begin Arrow type 20 Begin Arrow size End Arrow type 10 3,000 2,500 2,000 1,500 1,000 500 29 451E40? 1.09E40? 1.08E402 End Arrow size B.
Transcribed Image Text:Clipboard Font Alignment Number Styles Cells Editing Analysis Sensitivity Chart 5 fx В C E F G H K M Q R S Format Plot Area 1 v(cm-1) 3.99E+02 1.04E+02 1.03E+02 4.01E+02 1.08E+02 1.07E+02 4.03E+02 1.08E+02 1.07E+02 4.05E+02 1.06E+02 1.05E+02 4.07E+02 1.05E+02 1.06E+02 4.09E+02 1.06E+02 1.05E+02 4.11E+02 1.06E+02 1.05E+02 4.13E+02 1.06E+02 1.06E+02 |Chlorform Chlorform|D 110 O 2 Plot Area Options v 3 4 100 5 6 1 Border 90 7 O No line 8 9 O Solid line 80 10 4.15E+02 1.06E+02 1.06E+02 11 4.17E+02 1.07E+02 1.06E+02 12 4.18E+02 1.07E+02 1.06E+02 13 4.20E+02 1.06E+02 1.06E+02 14 4.22E+02 1.06E+02 1.06E+02 15 4.24E+02 1.06E+02 1.06E+02 16 4.26E+02 1.07E+02 1.06E+02 17 4.28E+02 1.08E+02 1.06E+02 18 4.30E+02 1.07E+02 1.06E+02 19 4.32E+02 1.07E+02 1.06E+02 20 4.34E+02 1.08E+02 1.06E+02 21 4.36E+02 1.08E+02 1.07E+02 22 4.38E+02 1.08E+02 1.06E+02 23 4.40E+02 1.07E+02 1.07E+02 24 4.42E+02 1.07E+02 1.07E+02 25 4.44E+02 1.08E+02 1.07E+02 26 4.45E+02 1.07E+02 1.07E+02 27 4.47E+02 1.08E+02 1.07E+02 28 4.49E+02 1.08E+02 1.08E+02 O Gradient line O Automatic 70 - Chlorform Chlorform D Color 60 Iransparency H 0% Width 1.75 pt 50 Compound type Dash type 40 Сap type Flat Join type Rounc 30 Begin Arrow type 20 Begin Arrow size End Arrow type 10 3,000 2,500 2,000 1,500 1,000 500 29 451E40? 1.09E40? 1.08E402 End Arrow size B.
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