Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Please solve and explain question 3

3) Give the structure of the charged fragments responsible for the indicated peaks in the
mass spectrum of butyrophenone. Hint: The fragment at m/z = 120 forms as a result of a
McLafferty rearrangement (see page 581 of Bruice).
m/z
Structure of charged fragment
148
120
105
77
Relative Intensity
100
80
60-
40-
20-
butyrophenone
H
25
50
77
75
105
100
120
125
m/z
Figure 3.9 The mass spectrum of butyrophenone.
148
150
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Transcribed Image Text:3) Give the structure of the charged fragments responsible for the indicated peaks in the mass spectrum of butyrophenone. Hint: The fragment at m/z = 120 forms as a result of a McLafferty rearrangement (see page 581 of Bruice). m/z Structure of charged fragment 148 120 105 77 Relative Intensity 100 80 60- 40- 20- butyrophenone H 25 50 77 75 105 100 120 125 m/z Figure 3.9 The mass spectrum of butyrophenone. 148 150
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