22 The absolute configuration of a chiral carbon is defined as R- or S- according to the Cahn-Ingold-Prelog rules What is the IUPAC name for the following compound? (1) (2) (3) (4) HO CH₂CH₂CH3 H (S) octan-5-ol (R) octan-4-ol (R) octan-5-ol (S) octan-4-ol CHỊCH,CHỊCH,
22 The absolute configuration of a chiral carbon is defined as R- or S- according to the Cahn-Ingold-Prelog rules What is the IUPAC name for the following compound? (1) (2) (3) (4) HO CH₂CH₂CH3 H (S) octan-5-ol (R) octan-4-ol (R) octan-5-ol (S) octan-4-ol CHỊCH,CHỊCH,
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Step 1: R/S absolute configuration rule
For the chiral carbon i.e. the carbon atom having four different groups attached to itself.
- If the 4th priority group is present at above the plane and the 1->2->3 priority groups are arranged in clockwise direction then the configuration will be 'S' or the 1->2->3 priority groups are arranged in anticlockwise direction then the configuration will be 'R'.
- If the 4th priority group is present at below the plane and the 1->2->3 priority groups are arranged in clockwise direction then the configuration will be 'R' or the 1->2->3 priority groups are arranged in anticlockwise direction then the configuration will be 'S'.
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