2. The conversion of parahydro into orthohydro was carried out at 923 K. The dependence of the half-life time (t) on the initial pressure is listed in the below table. Determine the order of the reaction. Assume that only parahydro was present at the beginning of the reaction. P (mmHg) t% (s) 50 648 100 450 200 400 318 222 ANS.: k=2.25 x 10-5 mmHg, sl, order of reaction: 1.5

Principles of Modern Chemistry
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Chapter18: Chemical Kinetics
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2. The conversion of parahydro into orthohydro was carried out at 923 K. The dependence of the
half-life time (t) on the initial pressure is listed in the below table. Determine the order of the
reaction. Assume that only parahydro was present at the beginning of the reaction.
P (mmHg)
t½ (S)
50
648
100
450
200
400
318
222
ANS.: k= 2.25 x 10-5 mmHg¨¹. s¹, order of reaction: 1.5
Transcribed Image Text:2. The conversion of parahydro into orthohydro was carried out at 923 K. The dependence of the half-life time (t) on the initial pressure is listed in the below table. Determine the order of the reaction. Assume that only parahydro was present at the beginning of the reaction. P (mmHg) t½ (S) 50 648 100 450 200 400 318 222 ANS.: k= 2.25 x 10-5 mmHg¨¹. s¹, order of reaction: 1.5
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