2 xs HX 1 X 1) xs NaNH2 2) H₂O R R 3 4 5 -CH3 R R H HgSO4 H2SO4, H₂O 1) R₂BH HX X2 (one equiv.) 2) H2O2, NaOH X R CCl4 6 R X X 1 X R 2) H₂O 1) xs NaNH2 XS X2 X X 1) NaNH2 2) RX 1) O3 2) H₂O CCl4 X R 7 9 8 H2 12 R R R R Lindlar's cat. + R OH O=C=0 H₂ Na R R 10 11 R Pt NH3 (1) R 2. Fill in the reagents for the synthesis shown below A В A: B: C: ABC HO

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution
Section16.SE: Something Extra
Problem 74AP: Identify the reagents represented by the letters a-e in the following scheme:
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2
xs HX
1
X
1) xs NaNH2
2) H₂O
R
R
3
4
5
-CH3
R
R
H
HgSO4
H2SO4, H₂O
1) R₂BH
HX
X2 (one equiv.)
2) H2O2, NaOH
X
R
CCl4
6
R
X
X
1
X
R
2) H₂O
1) xs NaNH2
XS X2
X X
1) NaNH2
2) RX
1) O3
2) H₂O
CCl4
X
R
7
9
8
H2
12
R
R
R
R
Lindlar's cat.
+
R
OH
O=C=0
H₂
Na
R
R
10
11 R
Pt
NH3 (1)
R
Transcribed Image Text:2 xs HX 1 X 1) xs NaNH2 2) H₂O R R 3 4 5 -CH3 R R H HgSO4 H2SO4, H₂O 1) R₂BH HX X2 (one equiv.) 2) H2O2, NaOH X R CCl4 6 R X X 1 X R 2) H₂O 1) xs NaNH2 XS X2 X X 1) NaNH2 2) RX 1) O3 2) H₂O CCl4 X R 7 9 8 H2 12 R R R R Lindlar's cat. + R OH O=C=0 H₂ Na R R 10 11 R Pt NH3 (1) R
2. Fill in the reagents for the synthesis shown below
A
В
A:
B:
C:
ABC
HO
Transcribed Image Text:2. Fill in the reagents for the synthesis shown below A В A: B: C: ABC HO
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