
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Transcribed Image Text:2- Find <a, a, a. a.> and <V> for the nth stationary state of H.O.
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- Consider the Dieterici equation for the pressure of a real gas (i) Find the dimension of the constant "a" and "b" P = RTe (an/VRT) (V/n)-barrow_forwardUsing the Van de Waals equation of state, derive the parameters a and b.arrow_forward4. The equation of state for a van der Waal's gas is: RT V-by², where Vm is the molar volume, V/n. p= m a m Starting with an expression for U(S,Vm), derive an expression for the internal pressure, TT, and calculate its change when a van der Waal's gas with a = 4.14 atm L²mol-2 and b = 5.15 x 10-2 Lmol-¹ is cooled from 200°C to 10°C.arrow_forward
- given these virial equations: Z = 1 + 2B’ p + 3 C’ p2 + D’ p3 + E’ p4 + ….. Z = 1 + 4B (1/Vm) + 5C (1/Vm)2 + D (1/Vm)3 + E (1/Vm)4+ …. where B’, B, C’, C, D’, D, E’ and E, etc, are virial coefficients; p is the pressure and Vm is the molar volume. how can i find the relation between B and B' and how do I determine the ratio of B'/B at T = 420 K from your expression?arrow_forwardA sample consisting of 3 mol of argon (monoatomic gas), initially at P1=352kPa and T1= 320K, is cooled reversibly to 240K at constant volume. Calculate the q. a. - 2992 J b. + 2992 J c. - 6255 J d. + 6255 Jarrow_forward
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